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Aluminum(III) di- and monochlorides incorporating an N,N'-chelating iminophosphonamide ligand: synthesis and structures

Kazuki Nakaya 1
Kazuki Nakaya
, 
Akihiko Ishii 1
Akihiko Ishii
, 
Norio Nakata 1
Norio Nakata
10.1016/j.mencom.2022.01.023
Published 2022-01-03
Communication , Volume 32, Issue 1, 71-73
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Nakaya K., Ishii A., Nakata N. Aluminum(III) di- and monochlorides incorporating an N,N'-chelating iminophosphonamide ligand: synthesis and structures // Mendeleev Communications. 2022. Vol. 32. No. 1. pp. 71-73.
GOST all authors (up to 50) Copy
Nakaya K., Ishii A., Nakata N. Aluminum(III) di- and monochlorides incorporating an N,N'-chelating iminophosphonamide ligand: synthesis and structures // Mendeleev Communications. 2022. Vol. 32. No. 1. pp. 71-73.
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TY - JOUR
DO - 10.1016/j.mencom.2022.01.023
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.01.023
TI - Aluminum(III) di- and monochlorides incorporating an N,N'-chelating iminophosphonamide ligand: synthesis and structures
T2 - Mendeleev Communications
AU - Nakaya, Kazuki
AU - Ishii, Akihiko
AU - Nakata, Norio
PY - 2022
DA - 2022/01/03
PB - Mendeleev Communications
SP - 71-73
IS - 1
VL - 32
ER -
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@article{2022_Nakaya,
author = {Kazuki Nakaya and Akihiko Ishii and Norio Nakata},
title = {Aluminum(III) di- and monochlorides incorporating an N,N'-chelating iminophosphonamide ligand: synthesis and structures},
journal = {Mendeleev Communications},
year = {2022},
volume = {32},
publisher = {Mendeleev Communications},
month = {Jan},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.01.023},
number = {1},
pages = {71--73},
doi = {10.1016/j.mencom.2022.01.023}
}
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Nakaya, Kazuki, et al. “Aluminum(III) di- and monochlorides incorporating an N,N'-chelating iminophosphonamide ligand: synthesis and structures.” Mendeleev Communications, vol. 32, no. 1, Jan. 2022, pp. 71-73. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.01.023.

Keywords

N,N'-chelating ligand
aluminum
cyclopentadienide
iminophosphonamide
nucleophilic substitution reaction
X-ray crystallography

Abstract

Treatment of lithium iminophosphonamide with AlCl3 in Et2O led to the formation of an aluminum(III) dichloride complex as colorless crystals. The substitution reactions of aluminum(III) dichloride stabilized by an iminophosphon- amide ligand with N- and Fe-nucleophiles gave the corresponding compounds of aluminum(III) monochloride. The reaction of the aluminum(III) dichloride complex with CpNa proceeded slowly at room temperature to form an aluminum(III) monochloride complex bearing an η1(σ)-bonded cyclopentadienyl ring.

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