Home / Publications / New coinage metal-coordinated intermetalloid E10 clusters (R3P)AuGe9(Hyp)3Pt(PPh3) (R = Bu, Et)

New coinage metal-coordinated intermetalloid E10 clusters (R3P)AuGe9(Hyp)3Pt(PPh3) (R = Bu, Et)

Christian Gienger 1
Christian Gienger
, 
Claudio Schrenk 1
Claudio Schrenk
, 
Andreas Schnepf 1
Andreas Schnepf
10.1016/j.mencom.2022.01.019
Published 2022-01-03
Communication , Volume 32, Issue 1, 60-62
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Gienger C., Schrenk C., Schnepf A. New coinage metal-coordinated intermetalloid E10 clusters (R3P)AuGe9(Hyp)3Pt(PPh3) (R = Bu, Et) // Mendeleev Communications. 2022. Vol. 32. No. 1. pp. 60-62.
GOST all authors (up to 50) Copy
Gienger C., Schrenk C., Schnepf A. New coinage metal-coordinated intermetalloid E10 clusters (R3P)AuGe9(Hyp)3Pt(PPh3) (R = Bu, Et) // Mendeleev Communications. 2022. Vol. 32. No. 1. pp. 60-62.
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TY - JOUR
DO - 10.1016/j.mencom.2022.01.019
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.01.019
TI - New coinage metal-coordinated intermetalloid E10 clusters (R3P)AuGe9(Hyp)3Pt(PPh3) (R = Bu, Et)
T2 - Mendeleev Communications
AU - Gienger, Christian
AU - Schrenk, Claudio
AU - Schnepf, Andreas
PY - 2022
DA - 2022/01/03
PB - Mendeleev Communications
SP - 60-62
IS - 1
VL - 32
ER -
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@article{2022_Gienger,
author = {Christian Gienger and Claudio Schrenk and Andreas Schnepf},
title = {New coinage metal-coordinated intermetalloid E10 clusters (R3P)AuGe9(Hyp)3Pt(PPh3) (R = Bu, Et)},
journal = {Mendeleev Communications},
year = {2022},
volume = {32},
publisher = {Mendeleev Communications},
month = {Jan},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.01.019},
number = {1},
pages = {60--62},
doi = {10.1016/j.mencom.2022.01.019}
}
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Gienger, Christian, et al. “New coinage metal-coordinated intermetalloid E10 clusters (R3P)AuGe9(Hyp)3Pt(PPh3) (R = Bu, Et).” Mendeleev Communications, vol. 32, no. 1, Jan. 2022, pp. 60-62. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.01.019.

Keywords

Cluster growth
germanium
Intermetalloid clusters
Metal insertion
NMR dynamics
X-ray diffraction

Abstract

We present the synthesis and characterization of the inter-metalloid clusters R3PAuGe9(Hyp)3Pt(PPh3) [R = Et, Bu; Hyp = Si(SiMe3)3] obtained by the reaction of R3PAuGe9(Hyp)3 (R = Et, Bu) with Pt(PPh3)4. The realized cluster enlargement is also known for the neutral cluster Ge9(Et)(Hyp)3, leading, however, to a different arrangement of substituents and different dynamics in the solution.

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