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Effective synthesis of dialkyl carbonate from CO2 and alcohols using dibutyltin(IV) oxide catalyst and dehydrating agents

Wahyu S Putro 1
Wahyu S Putro
, 
Yusuke Munakata 1, 2
Yusuke Munakata
, 
Shinji Shigeyasu 3
Shinji Shigeyasu
, 
Satoshi Hamura 3
Satoshi Hamura
, 
Seiji Matsumoto 3
Seiji Matsumoto
, 
Jun-Chul Choi 1, 2
Jun-Chul Choi
, 
Norihisa Fukaya 1
Norihisa Fukaya
10.1016/j.mencom.2022.01.017
Published 2022-01-03
Communication , Volume 32, Issue 1, 54-56
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Putro W. S. et al. Effective synthesis of dialkyl carbonate from CO2 and alcohols using dibutyltin(IV) oxide catalyst and dehydrating agents // Mendeleev Communications. 2022. Vol. 32. No. 1. pp. 54-56.
GOST all authors (up to 50) Copy
Putro W. S., Munakata Y., Shigeyasu S., Hamura S., Matsumoto S., Choi J., Fukaya N. Effective synthesis of dialkyl carbonate from CO2 and alcohols using dibutyltin(IV) oxide catalyst and dehydrating agents // Mendeleev Communications. 2022. Vol. 32. No. 1. pp. 54-56.
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TY - JOUR
DO - 10.1016/j.mencom.2022.01.017
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.01.017
TI - Effective synthesis of dialkyl carbonate from CO2 and alcohols using dibutyltin(IV) oxide catalyst and dehydrating agents
T2 - Mendeleev Communications
AU - Putro, Wahyu S
AU - Munakata, Yusuke
AU - Shigeyasu, Shinji
AU - Hamura, Satoshi
AU - Matsumoto, Seiji
AU - Choi, Jun-Chul
AU - Fukaya, Norihisa
PY - 2022
DA - 2022/01/03
PB - Mendeleev Communications
SP - 54-56
IS - 1
VL - 32
ER -
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@article{2022_Putro,
author = {Wahyu S Putro and Yusuke Munakata and Shinji Shigeyasu and Satoshi Hamura and Seiji Matsumoto and Jun-Chul Choi and Norihisa Fukaya},
title = {Effective synthesis of dialkyl carbonate from CO2 and alcohols using dibutyltin(IV) oxide catalyst and dehydrating agents},
journal = {Mendeleev Communications},
year = {2022},
volume = {32},
publisher = {Mendeleev Communications},
month = {Jan},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.01.017},
number = {1},
pages = {54--56},
doi = {10.1016/j.mencom.2022.01.017}
}
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Putro, Wahyu S., et al. “Effective synthesis of dialkyl carbonate from CO2 and alcohols using dibutyltin(IV) oxide catalyst and dehydrating agents.” Mendeleev Communications, vol. 32, no. 1, Jan. 2022, pp. 54-56. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.01.017.

Abstract

The combination of a dibutyltin(IV) oxide catalyst with an ortho ester as the dehydrating agent exhibited high activity for the direct synthesis of diethyl carbonate from CO2 and ethanol in 78% yield. With water as a by-product limiting the reaction, a recoverable dehydrating agent is required. When alkoxysilanes were employed for this purpose, various dialkyl carbonates were obtained in yields of 33–45%.

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