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Elimination of bis(trimethylsilyl)stannylene from tris(trimethylsilyl)stannylated zirconocene and hafnocene chlorides

Roland Fischer 1
Roland Fischer
, 
Christoph Marschner 1
Christoph Marschner
10.1016/j.mencom.2022.01.016
Published 2022-01-03
Communication , Volume 32, Issue 1, 52-53
2
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Fischer R., Marschner C. Elimination of bis(trimethylsilyl)stannylene from tris(trimethylsilyl)stannylated zirconocene and hafnocene chlorides // Mendeleev Communications. 2022. Vol. 32. No. 1. pp. 52-53.
GOST all authors (up to 50) Copy
Fischer R., Marschner C. Elimination of bis(trimethylsilyl)stannylene from tris(trimethylsilyl)stannylated zirconocene and hafnocene chlorides // Mendeleev Communications. 2022. Vol. 32. No. 1. pp. 52-53.
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TY - JOUR
DO - 10.1016/j.mencom.2022.01.016
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.01.016
TI - Elimination of bis(trimethylsilyl)stannylene from tris(trimethylsilyl)stannylated zirconocene and hafnocene chlorides
T2 - Mendeleev Communications
AU - Fischer, Roland
AU - Marschner, Christoph
PY - 2022
DA - 2022/01/03
PB - Mendeleev Communications
SP - 52-53
IS - 1
VL - 32
ER -
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@article{2022_Fischer,
author = {Roland Fischer and Christoph Marschner},
title = {Elimination of bis(trimethylsilyl)stannylene from tris(trimethylsilyl)stannylated zirconocene and hafnocene chlorides},
journal = {Mendeleev Communications},
year = {2022},
volume = {32},
publisher = {Mendeleev Communications},
month = {Jan},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.01.016},
number = {1},
pages = {52--53},
doi = {10.1016/j.mencom.2022.01.016}
}
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Fischer, Roland, and Christoph Marschner. “Elimination of bis(trimethylsilyl)stannylene from tris(trimethylsilyl)stannylated zirconocene and hafnocene chlorides.” Mendeleev Communications, vol. 32, no. 1, Jan. 2022, pp. 52-53. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.01.016.

Keywords

Group 4 elements
hafnium
Metallocenes
silicon
Stannylated compounds
Stannylene
tin
zirconium

Abstract

Reactions of (Me3Si)3SnK with Cp2MCl2 (M = Zr, Hf) give the respective stannylated metallocene chlorides. These complexes display a tendency to eliminate bis(trimethylsilyl)-stannylene under Cp2M(Cl)SiMe3 formation.

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