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A phenyl-substituted germole dianion and its reaction with hafnocene dichloride

Hanna H Cramer 1
Hanna H Cramer
, 
Lukas Bührmann 1
Lukas Bührmann
, 
Marc Schmidtmann 1
Marc Schmidtmann
, 
Thomas Müller 1
Thomas Müller
10.1016/j.mencom.2022.01.014
Published 2022-01-03
Communication , Volume 32, Issue 1, 46-48
3
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Cramer H. H. et al. A phenyl-substituted germole dianion and its reaction with hafnocene dichloride // Mendeleev Communications. 2022. Vol. 32. No. 1. pp. 46-48.
GOST all authors (up to 50) Copy
Cramer H. H., Bührmann L., Schmidtmann M., Müller T. A phenyl-substituted germole dianion and its reaction with hafnocene dichloride // Mendeleev Communications. 2022. Vol. 32. No. 1. pp. 46-48.
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TY - JOUR
DO - 10.1016/j.mencom.2022.01.014
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.01.014
TI - A phenyl-substituted germole dianion and its reaction with hafnocene dichloride
T2 - Mendeleev Communications
AU - Cramer, Hanna H
AU - Bührmann, Lukas
AU - Schmidtmann, Marc
AU - Müller, Thomas
PY - 2022
DA - 2022/01/03
PB - Mendeleev Communications
SP - 46-48
IS - 1
VL - 32
ER -
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@article{2022_Cramer,
author = {Hanna H Cramer and Lukas Bührmann and Marc Schmidtmann and Thomas Müller},
title = {A phenyl-substituted germole dianion and its reaction with hafnocene dichloride},
journal = {Mendeleev Communications},
year = {2022},
volume = {32},
publisher = {Mendeleev Communications},
month = {Jan},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.01.014},
number = {1},
pages = {46--48},
doi = {10.1016/j.mencom.2022.01.014}
}
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Cramer, Hanna H., et al. “A phenyl-substituted germole dianion and its reaction with hafnocene dichloride.” Mendeleev Communications, vol. 32, no. 1, Jan. 2022, pp. 46-48. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.01.014.

Keywords

Anions
aromaticity
germanium
Germoles
Hafnium complexes
organogermanium compounds

Abstract

The reaction of phenyl-substituted dipotassium germacyclo-pentadienediide with one equivalent of hafnocene dichloride at low temperature provides a bicyclic germylene. With two equivalents of hafnocene dichloride, a dinuclear hafnium complex with a mmm-coordinating germolyl dianion ligand is formed.

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