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The influence of differently substituted cyclopentadienyl CpR ligands on the reactivity of [CpRFe(CO)2]2 with yellow arsenic

Hannes Krauss 1
Hannes Krauss
, 
Gábor Balazs 1
Gábor Balazs
, 
Michael Seidl 1
Michael Seidl
, 
Manfred Scheer 1
Manfred Scheer
10.1016/j.mencom.2022.01.013
Published 2022-01-03
Communication , Volume 32, Issue 1, 42-45
4
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Krauss H. et al. The influence of differently substituted cyclopentadienyl CpR ligands on the reactivity of [CpRFe(CO)2]2 with yellow arsenic // Mendeleev Communications. 2022. Vol. 32. No. 1. pp. 42-45.
GOST all authors (up to 50) Copy
Krauss H., Balazs G., Seidl M., Scheer M. The influence of differently substituted cyclopentadienyl CpR ligands on the reactivity of [CpRFe(CO)2]2 with yellow arsenic // Mendeleev Communications. 2022. Vol. 32. No. 1. pp. 42-45.
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TY - JOUR
DO - 10.1016/j.mencom.2022.01.013
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.01.013
TI - The influence of differently substituted cyclopentadienyl CpR ligands on the reactivity of [CpRFe(CO)2]2 with yellow arsenic
T2 - Mendeleev Communications
AU - Krauss, Hannes
AU - Balazs, Gábor
AU - Seidl, Michael
AU - Scheer, Manfred
PY - 2022
DA - 2022/01/03
PB - Mendeleev Communications
SP - 42-45
IS - 1
VL - 32
ER -
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@article{2022_Krauss,
author = {Hannes Krauss and Gábor Balazs and Michael Seidl and Manfred Scheer},
title = {The influence of differently substituted cyclopentadienyl CpR ligands on the reactivity of [CpRFe(CO)2]2 with yellow arsenic},
journal = {Mendeleev Communications},
year = {2022},
volume = {32},
publisher = {Mendeleev Communications},
month = {Jan},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.01.013},
number = {1},
pages = {42--45},
doi = {10.1016/j.mencom.2022.01.013}
}
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Krauss, Hannes, et al. “The influence of differently substituted cyclopentadienyl CpR ligands on the reactivity of [CpRFe(CO)2]2 with yellow arsenic.” Mendeleev Communications, vol. 32, no. 1, Jan. 2022, pp. 42-45. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.01.013.

Keywords

Cyclopentadienyl ligands
iron complexes
oxidation
Polyarsenic ligand complexes
Yellow arsenic

Abstract

The influence of differently substituted cyclopentadienyl CpR ligands on the reaction outcome of [CpRFe(CO)2]2 (CpR = C5Me5, EtC5Me4, 1,3-Bu2tC5H3) with As4 is examined. For C5Me5 and EtC5Me4, the pentaarsaferrocene derivatives [CpRFe(η5-As5)] are formed together with [(CpRFe)3As6] and [(CpRFe)3As6{(η3-As3)Fe}], while for 1,3-Bu2tC5H3 only [(CpRFe)3As6] is formed. The reaction of [(Me5C5Fe)3As6{(η3-As3)Fe}] with Tl+ leads to [{(Me5C5Fe)3As6Fe}2(μ,η3:η3-As3)]2+ representing an unexpected dicationic cluster.

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