Home / Publications / Synthesis and structure of (O → Si)-chelate fluorosilane, a novel complex of pentacoordinate silicon with N-acetylvaline

Synthesis and structure of (O → Si)-chelate fluorosilane, a novel complex of pentacoordinate silicon with N-acetylvaline

Alexey Aleksandrovich Nikolin 1
Alexey Aleksandrovich Nikolin
, 
Alexander Aleksandrovich Korlyukov 1, 2
Alexander Aleksandrovich Korlyukov
, 
Eugeniya Petrovna Kramarova 1
Eugeniya Petrovna Kramarova
,  , 
Dmitry Evgen'evich Arkhipov 2
Dmitry Evgen'evich Arkhipov
, 
Dmitry Victorovich Tarasenko 1
Dmitry Victorovich Tarasenko
, 
Sergey Yur'evich Bylikin 4
Sergey Yur'evich Bylikin
, 
Yuri Ivanovich Baukov 1
Yuri Ivanovich Baukov
, 
Vadim Vital'evich Negrebetsky 1
Vadim Vital'evich Negrebetsky
10.1016/j.mencom.2022.01.011
Published 2022-01-03
Communication , Volume 32, Issue 1, 37-38
7
Share
Cite this
GOST
 | 
Cite this
GOST Copy
Nikolin A. A. et al. Synthesis and structure of (O → Si)-chelate fluorosilane, a novel complex of pentacoordinate silicon with N-acetylvaline // Mendeleev Communications. 2022. Vol. 32. No. 1. pp. 37-38.
GOST all authors (up to 50) Copy
Nikolin A. A., Korlyukov A. A., Kramarova E. P., Romanenko A. R., Arkhipov D. E., Tarasenko D. V., Bylikin S. Y., Baukov Y. I., Negrebetsky V. V. Synthesis and structure of (O → Si)-chelate fluorosilane, a novel complex of pentacoordinate silicon with N-acetylvaline // Mendeleev Communications. 2022. Vol. 32. No. 1. pp. 37-38.
RIS
 | 
Cite this
RIS Copy
TY - JOUR
DO - 10.1016/j.mencom.2022.01.011
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.01.011
TI - Synthesis and structure of (O → Si)-chelate fluorosilane, a novel complex of pentacoordinate silicon with N-acetylvaline
T2 - Mendeleev Communications
AU - Nikolin, Alexey Aleksandrovich
AU - Korlyukov, Alexander Aleksandrovich
AU - Kramarova, Eugeniya Petrovna
AU - Romanenko, Alexandr Romanovich
AU - Arkhipov, Dmitry Evgen'evich
AU - Tarasenko, Dmitry Victorovich
AU - Bylikin, Sergey Yur'evich
AU - Baukov, Yuri Ivanovich
AU - Negrebetsky, Vadim Vital'evich
PY - 2022
DA - 2022/01/03
PB - Mendeleev Communications
SP - 37-38
IS - 1
VL - 32
ER -
BibTex
 | 
Cite this
BibTex (up to 50 authors) Copy
@article{2022_Nikolin,
author = {Alexey Aleksandrovich Nikolin and Alexander Aleksandrovich Korlyukov and Eugeniya Petrovna Kramarova and Alexandr Romanovich Romanenko and Dmitry Evgen'evich Arkhipov and Dmitry Victorovich Tarasenko and Sergey Yur'evich Bylikin and Yuri Ivanovich Baukov and Vadim Vital'evich Negrebetsky},
title = {Synthesis and structure of (O → Si)-chelate fluorosilane, a novel complex of pentacoordinate silicon with N-acetylvaline},
journal = {Mendeleev Communications},
year = {2022},
volume = {32},
publisher = {Mendeleev Communications},
month = {Jan},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.01.011},
number = {1},
pages = {37--38},
doi = {10.1016/j.mencom.2022.01.011}
}
MLA
Cite this
MLA Copy
Nikolin, Alexey Aleksandrovich, et al. “Synthesis and structure of (O → Si)-chelate fluorosilane, a novel complex of pentacoordinate silicon with N-acetylvaline.” Mendeleev Communications, vol. 32, no. 1, Jan. 2022, pp. 37-38. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.01.011.

Abstract

A novel organosilicon complex of N-acetylvaline was synthesized by the reaction of the relative disiloxane derivative with BF3 etherate. According to X-ray and NMR data, the silicon atom of the final product is pentacoordinated in both the solid state and solution. The coordination state of silicon was correctly predicted by quantum-chemical calculations.

References

1.
10.1016/j.mencom.2022.01.011_b0005
The Chemistry of Organic Silicon Compounds, 1998
2.
10.1016/j.mencom.2022.01.011_b0010
Voronkov
Organomet. Chem. USSR, 1991
4.
Stereochemical non-rigidity of complexes of hypercoordinate Group 14 elements
Negrebetsky V.V., Tandura S.N., Baukov Y.I.
Russian Chemical Reviews, 2009
6.
Hypervalent silicon-containing organosilicon derivatives of nitrogen heterocycles
Voronkov M.G., Trofimova O.M., Bolgova Y.I., Chernov N.F.
Russian Chemical Reviews, 2007
7.
Hydrazide-Based Hypercoordinate Silicon Compounds
KOST D., Kalikhman I.
Advances in Organometallic Chemistry, 2004
8.
New disiloxane based on N-acetylvaline: synthesis and structure
Nikolin A.A., Korlyukov A.A., Kramarova E.P., Arkhipov D.E., Shipov A.G., Baukov Y.I., Negrebetsky V.V.
Russian Chemical Bulletin, 2018
9.
A short history of SHELX
Sheldrick G.M.
Acta Crystallographica Section A Foundations of Crystallography, 2007
10.
OLEX2: a complete structure solution, refinement and analysis program
Dolomanov O.V., Bourhis L.J., Gildea R.J., Howard J.A., Puschmann H.
Journal of Applied Crystallography, 2009
11.
10.1016/j.mencom.2022.01.011_b0055
Nikolin
Russ. Chem. Bull., Int. Ed., 2013
12.
Mono-C,O-chelated bromo- and triflatosilanes with an amino acid moiety: salts or covalently bonded complexes?
Korlyukov A.A., Arkhipov D.E., Volodin A.D., Negrebetskii V.V., Nikolin A.A., Kramarova E.P., Shipov A.G., Baukov Y.I.
Russian Chemical Bulletin, 2019
16.
10.1016/j.mencom.2022.01.011_b0080
Frisch
Gaussian 03, Revision C. 01, 2004
17.
Multiwfn: A multifunctional wavefunction analyzer
Lu T., Chen F.
Journal of Computational Chemistry, 2011