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Phosphatetrasilatricyclo[2.1.0.02,5]pentane

, 
Takahiko Meguro 1
Takahiko Meguro
, 
Olga Aleksandrovna Gapurenko 2
Olga Aleksandrovna Gapurenko
, 
Ruslan Mikhailovich Minyaev 2
Ruslan Mikhailovich Minyaev
, 
Vladimir Isaakovich Minkin 2
Vladimir Isaakovich Minkin
, 
Heinz Gornitzka 3
Heinz Gornitzka
, 
Akira Sekiguchi 1
Akira Sekiguchi
10.1016/j.mencom.2022.01.009
Published 2022-01-03
Communication , Volume 32, Issue 1, 33-34
2
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Lee V. Y. et al. Phosphatetrasilatricyclo[2.1.0.02,5]pentane // Mendeleev Communications. 2022. Vol. 32. No. 1. pp. 33-34.
GOST all authors (up to 50) Copy
Lee V. Y., Meguro T., Gapurenko O. A., Minyaev R. M., Minkin V. I., Gornitzka H., Sekiguchi A. Phosphatetrasilatricyclo[2.1.0.02,5]pentane // Mendeleev Communications. 2022. Vol. 32. No. 1. pp. 33-34.
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TY - JOUR
DO - 10.1016/j.mencom.2022.01.009
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.01.009
TI - Phosphatetrasilatricyclo[2.1.0.02,5]pentane
T2 - Mendeleev Communications
AU - Lee, Vladimir Yaroslavovich
AU - Meguro, Takahiko
AU - Gapurenko, Olga Aleksandrovna
AU - Minyaev, Ruslan Mikhailovich
AU - Minkin, Vladimir Isaakovich
AU - Gornitzka, Heinz
AU - Sekiguchi, Akira
PY - 2022
DA - 2022/01/03
PB - Mendeleev Communications
SP - 33-34
IS - 1
VL - 32
ER -
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@article{2022_Lee,
author = {Vladimir Yaroslavovich Lee and Takahiko Meguro and Olga Aleksandrovna Gapurenko and Ruslan Mikhailovich Minyaev and Vladimir Isaakovich Minkin and Heinz Gornitzka and Akira Sekiguchi},
title = {Phosphatetrasilatricyclo[2.1.0.02,5]pentane},
journal = {Mendeleev Communications},
year = {2022},
volume = {32},
publisher = {Mendeleev Communications},
month = {Jan},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.01.009},
number = {1},
pages = {33--34},
doi = {10.1016/j.mencom.2022.01.009}
}
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Lee, Vladimir Yaroslavovich, et al. “Phosphatetrasilatricyclo[2.1.0.02,5]pentane.” Mendeleev Communications, vol. 32, no. 1, Jan. 2022, pp. 33-34. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.01.009.

Keywords

DFT calculations
housene
phosphorus
silicon
tricyclo[2.1.0.025]pentane
X-ray diffraction

Abstract

The phosphatetrasilatricyclo[2.1.0.02,5]pentane cage compound was synthesized by the reaction of the tetrasilacyclobutadiene dianion dipotassium salt precursor with PCl3. The structure, bonding nature, and mechanism of formation of the title compound were studied both experimentally (NMR, X-ray) and computationally (DFT).

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