Home / Publications / η2-Phosphasilene transition metal complexes – a novel building block for hetero-multimetallic complexes

η2-Phosphasilene transition metal complexes – a novel building block for hetero-multimetallic complexes

Boris Minkovich 1
Boris Minkovich
, 
Alexander Kaushansky 1
Alexander Kaushansky
, 
Natalia Fridman 1
Natalia Fridman
, 
Dmitry Al'bertovich Bravo-Zhivotovskii 1
Dmitry Al'bertovich Bravo-Zhivotovskii
, 
Yitzhak Apeloig 1
Yitzhak Apeloig
10.1016/j.mencom.2022.01.008
Published 2022-01-03
Communication , Volume 32, Issue 1, 28-32
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Minkovich B. et al. η2-Phosphasilene transition metal complexes – a novel building block for hetero-multimetallic complexes // Mendeleev Communications. 2022. Vol. 32. No. 1. pp. 28-32.
GOST all authors (up to 50) Copy
Minkovich B., Kaushansky A., Fridman N., Bravo-Zhivotovskii D. A., Apeloig Y. η2-Phosphasilene transition metal complexes – a novel building block for hetero-multimetallic complexes // Mendeleev Communications. 2022. Vol. 32. No. 1. pp. 28-32.
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TY - JOUR
DO - 10.1016/j.mencom.2022.01.008
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.01.008
TI - η2-Phosphasilene transition metal complexes – a novel building block for hetero-multimetallic complexes
T2 - Mendeleev Communications
AU - Minkovich, Boris
AU - Kaushansky, Alexander
AU - Fridman, Natalia
AU - Bravo-Zhivotovskii, Dmitry Al'bertovich
AU - Apeloig, Yitzhak
PY - 2022
DA - 2022/01/03
PB - Mendeleev Communications
SP - 28-32
IS - 1
VL - 32
ER -
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@article{2022_Minkovich,
author = {Boris Minkovich and Alexander Kaushansky and Natalia Fridman and Dmitry Al'bertovich Bravo-Zhivotovskii and Yitzhak Apeloig},
title = {η2-Phosphasilene transition metal complexes – a novel building block for hetero-multimetallic complexes},
journal = {Mendeleev Communications},
year = {2022},
volume = {32},
publisher = {Mendeleev Communications},
month = {Jan},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.01.008},
number = {1},
pages = {28--32},
doi = {10.1016/j.mencom.2022.01.008}
}
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Minkovich, Boris, et al. “η2-Phosphasilene transition metal complexes – a novel building block for hetero-multimetallic complexes.” Mendeleev Communications, vol. 32, no. 1, Jan. 2022, pp. 28-32. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.01.008.

Keywords

heavy main-group multiple bonds
hetero-bimetallic complex
NMR
phosphasilene
phosphorus
silicon
transition metal complex
X-ray structures
π-complex

Abstract

Compound η2-((R3Si)2Si=PH)–Pt(dmpe) was synthesized by trapping the transient phosphasilene, (R3Si)2Si=PH. Novel hetero-bi- and tri-metallic complexes derived from η2-((R3Si)2Si=PH)–Pt(dmpe) containing Pt with Li, Zn, Hg and Ag metals were synthesized and characterized by multi- nuclear NMR spectroscopy and X-ray crystallography. The synthesis of η2-((R3Si)2Si=PH)–Pt(dmpe), and its bonding character are discussed; a 1,2-silyl shift from silicon to phosphorus (a ‘Brook-type’ rearrangement) within the coordination sphere of a Pt complex is also reported.

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