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New insights into the selective and systematic preparation of arylgermanium hydrides

Ana Torvisco 1
Ana Torvisco
, 
Melanie Wolf 1
Melanie Wolf
, 
Michael Traxler 1
Michael Traxler
, 
Dietrich Gudat 2
Dietrich Gudat
, 
Frank Uhlig 1
Frank Uhlig
10.1016/j.mencom.2022.01.006
Published 2022-01-03
Communication , Volume 32, Issue 1, 22-24
4
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Torvisco A. et al. New insights into the selective and systematic preparation of arylgermanium hydrides // Mendeleev Communications. 2022. Vol. 32. No. 1. pp. 22-24.
GOST all authors (up to 50) Copy
Torvisco A., Wolf M., Traxler M., Gudat D., Uhlig F. New insights into the selective and systematic preparation of arylgermanium hydrides // Mendeleev Communications. 2022. Vol. 32. No. 1. pp. 22-24.
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TY - JOUR
DO - 10.1016/j.mencom.2022.01.006
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.01.006
TI - New insights into the selective and systematic preparation of arylgermanium hydrides
T2 - Mendeleev Communications
AU - Torvisco, Ana
AU - Wolf, Melanie
AU - Traxler, Michael
AU - Gudat, Dietrich
AU - Uhlig, Frank
PY - 2022
DA - 2022/01/03
PB - Mendeleev Communications
SP - 22-24
IS - 1
VL - 32
ER -
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@article{2022_Torvisco,
author = {Ana Torvisco and Melanie Wolf and Michael Traxler and Dietrich Gudat and Frank Uhlig},
title = {New insights into the selective and systematic preparation of arylgermanium hydrides},
journal = {Mendeleev Communications},
year = {2022},
volume = {32},
publisher = {Mendeleev Communications},
month = {Jan},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.01.006},
number = {1},
pages = {22--24},
doi = {10.1016/j.mencom.2022.01.006}
}
MLA
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MLA Copy
Torvisco, Ana, et al. “New insights into the selective and systematic preparation of arylgermanium hydrides.” Mendeleev Communications, vol. 32, no. 1, Jan. 2022, pp. 22-24. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.01.006.

Keywords

1H NMR spectroscopy
73Ge NMR spectroscopy
aryl(chloro)germanium hydrides
arylgermanium hydrides
organogermanium compounds
solid-state structures

Abstract

A series of novel arylgermanium hydrides ArnGeH4–n (n = 1–3) and diaryl(chloro)germanium hydrides Ar2Ge(Cl)H were synthesized and characterized. Systematic preparation and purification were achieved via the lithium chloride–triflic acid and the optimized Grignard route. Arylgermanium hydrides ArnGeH4–n (Ar = 2,5-Me2C6H3, n = 1–3) were characterized by 1H and 73Ge NMR spectroscopy and single crystal X-ray diffractometry.

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