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A facile route to germanium(IV) binaphthoxide complexes: crystal structure of a chiral resolved germanium(IV) binaphthoxide

Miguel A.,Jr Leal 1
Miguel A.,Jr Leal
, 
Arnold L Rheingold 2
Arnold L Rheingold
, 
Charles Scott Weinert 1
Charles Scott Weinert
10.1016/j.mencom.2022.01.005
Published 2022-01-03
Communication , Volume 32, Issue 1, 19-21
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Leal M. A., Rheingold A. L., Weinert C. S. A facile route to germanium(IV) binaphthoxide complexes: crystal structure of a chiral resolved germanium(IV) binaphthoxide // Mendeleev Communications. 2022. Vol. 32. No. 1. pp. 19-21.
GOST all authors (up to 50) Copy
Leal M. A., Rheingold A. L., Weinert C. S. A facile route to germanium(IV) binaphthoxide complexes: crystal structure of a chiral resolved germanium(IV) binaphthoxide // Mendeleev Communications. 2022. Vol. 32. No. 1. pp. 19-21.
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TY - JOUR
DO - 10.1016/j.mencom.2022.01.005
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.01.005
TI - A facile route to germanium(IV) binaphthoxide complexes: crystal structure of a chiral resolved germanium(IV) binaphthoxide
T2 - Mendeleev Communications
AU - Leal, Miguel A.,Jr
AU - Rheingold, Arnold L
AU - Weinert, Charles Scott
PY - 2022
DA - 2022/01/03
PB - Mendeleev Communications
SP - 19-21
IS - 1
VL - 32
ER -
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@article{2022_Leal,
author = {Miguel A.,Jr Leal and Arnold L Rheingold and Charles Scott Weinert},
title = {A facile route to germanium(IV) binaphthoxide complexes: crystal structure of a chiral resolved germanium(IV) binaphthoxide},
journal = {Mendeleev Communications},
year = {2022},
volume = {32},
publisher = {Mendeleev Communications},
month = {Jan},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.01.005},
number = {1},
pages = {19--21},
doi = {10.1016/j.mencom.2022.01.005}
}
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Leal, Miguel A.,Jr, et al. “A facile route to germanium(IV) binaphthoxide complexes: crystal structure of a chiral resolved germanium(IV) binaphthoxide.” Mendeleev Communications, vol. 32, no. 1, Jan. 2022, pp. 19-21. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.01.005.

Keywords

aryl oxides
chiral binaphthoxides
crystal structure
germanium
metathesis reactions
organogermanium compounds
phenylgermanium trichloride

Abstract

A method for the facile synthesis of chiral germanium(IV) binaphthoxide complexes from the corresponding binaphthols and an organogermanium trichloride has been developed, which allows these unusual types of compounds to be synthesized in high yields. The crystal structure of one such complex, (S)-[Ge{O2C20H10(SiMe3)2-3,3'}{Cl}{Ph}], has been determined.

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