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Effect of a long-term exposure of anatase TiO2 powder doped with surface-located Sb3+ ions to UV radiation on its photocatalytic activity

Mikhail Vladimirovich Korolenko 1
Mikhail Vladimirovich Korolenko
, 
Pavel Borisovich Fabrichnyi 1
Pavel Borisovich Fabrichnyi
, 
10.1016/j.mencom.2021.11.043
Published 2021-11-08
Communication , Volume 31, Issue 6, 896-898
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Korolenko M. V., Fabrichnyi P. B., Afanasov M. I. Effect of a long-term exposure of anatase TiO2 powder doped with surface-located Sb3+ ions to UV radiation on its photocatalytic activity // Mendeleev Communications. 2021. Vol. 31. No. 6. pp. 896-898.
GOST all authors (up to 50) Copy
Korolenko M. V., Fabrichnyi P. B., Afanasov M. I. Effect of a long-term exposure of anatase TiO2 powder doped with surface-located Sb3+ ions to UV radiation on its photocatalytic activity // Mendeleev Communications. 2021. Vol. 31. No. 6. pp. 896-898.
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TY - JOUR
DO - 10.1016/j.mencom.2021.11.043
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.11.043
TI - Effect of a long-term exposure of anatase TiO2 powder doped with surface-located Sb3+ ions to UV radiation on its photocatalytic activity
T2 - Mendeleev Communications
AU - Korolenko, Mikhail Vladimirovich
AU - Fabrichnyi, Pavel Borisovich
AU - Afanasov, Mikhail Ivanovich
PY - 2021
DA - 2021/11/08
PB - Mendeleev Communications
SP - 896-898
IS - 6
VL - 31
ER -
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@article{2021_Korolenko,
author = {Mikhail Vladimirovich Korolenko and Pavel Borisovich Fabrichnyi and Mikhail Ivanovich Afanasov},
title = {Effect of a long-term exposure of anatase TiO2 powder doped with surface-located Sb3+ ions to UV radiation on its photocatalytic activity},
journal = {Mendeleev Communications},
year = {2021},
volume = {31},
publisher = {Mendeleev Communications},
month = {Nov},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.11.043},
number = {6},
pages = {896--898},
doi = {10.1016/j.mencom.2021.11.043}
}
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Korolenko, Mikhail Vladimirovich, et al. “Effect of a long-term exposure of anatase TiO2 powder doped with surface-located Sb3+ ions to UV radiation on its photocatalytic activity.” Mendeleev Communications, vol. 31, no. 6, Nov. 2021, pp. 896-898. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.11.043.

Keywords

121Sb Mössbauer spectroscopy
methyl orange
photocatalytic decolorization
Sb-doped TiO2
Sb3+ electronic lone pair
stereochemical activity

Abstract

Ultraviolet photocatalytic experiments on the kinetics of decolorization of methyl orange and the 121Sb Mössbauer characterization of the title catalyst were performed. The stereochemically active electronic lone pair of Sb3+ was found to completely deactivate the neighboring oxygen vacancy as a recombination center towards the photogenerated electrons and holes.

References

1.
Successful location of tin dopant cations on surface sites of anatase-type TiO2 crystallites evidenced by 119Sn Mössbauer spectroscopic probe and XPS techniques
Astashkin R.A., Fabritchnyi P.B., Afanasov M.I., Korolenko M.V., Wattiaux A., Bordère S., Labrugère C., Delmas C.
Solid State Sciences, 2013
2.
Manifestation of the photocatalytic activity of anatase powders in Mössbauer spectra of 121Sb probe nuclei
Korolenko M.V., Fabrichnyi P.B., Afanasov M.I., Labrugère C.
Bulletin of the Russian Academy of Sciences: Physics, 2015
3.
10.1016/j.mencom.2021.11.043_b0015
Yadav
J. Mater. Sci.: Mater. Electron., 2016
4.
Photocatalysis with Chromium-Doped TiO2: Bulk and Surface Doping
Ould-Chikh S., Proux O., Afanasiev P., Khrouz L., Hedhili M.N., Anjum D.H., Harb M., Geantet C., Basset J., Puzenat E.
ChemSusChem, 2014
5.
Recent Developments of TiO2-Based Photocatalysis in the Hydrogen Evolution and Photodegradation: A Review
Bakbolat B., Daulbayev C., Sultanov F., Beissenov R., Umirzakov A., Mereke A., Bekbaev A., Chuprakov I.
Nanomaterials, 2020
6.
Korolenko M.V., Fabritchnyi P.B., Afanasov M.I.
Mendeleev Communications, 2020
7.
Photoinduced Dynamics of TiO2 Doped with Cr and Sb
Ikeda T., Nomoto T., Eda K., Mizutani Y., Kato H., Kudo A., Onishi H.
Journal of Physical Chemistry C, 2008
10.
121Sb Mössbauer spectra of antimony oxides
Long G.G., Stevens J.G., Bowen L.H.
Inorganic and Nuclear Chemistry Letters, 1969
12.
Antimony-121 mössbauer spectra of antimony (III) compounds with a stereochemically active lone pair
Takeda M., Takahashi M., Ohyama R., Nakai I.
Hyperfine Interactions, 1986