Home / Publications / Phase equilibrium in the ternary system water–ethylene glycol–dimethyl sulfoxide

Phase equilibrium in the ternary system water–ethylene glycol–dimethyl sulfoxide

Irina Aleksandrovna Solonina 1
Irina Aleksandrovna Solonina
, 
Mikhail Romanovich Kiselev 2
Mikhail Romanovich Kiselev
,  , 
Margarita Nikolaevna Rodnikova 1
Margarita Nikolaevna Rodnikova
10.1016/j.mencom.2021.11.041
Published 2021-11-08
Communication , Volume 31, Issue 6, 890-892
1
Share
Cite this
GOST
 | 
Cite this
GOST Copy
Solonina I. A. et al. Phase equilibrium in the ternary system water–ethylene glycol–dimethyl sulfoxide // Mendeleev Communications. 2021. Vol. 31. No. 6. pp. 890-892.
GOST all authors (up to 50) Copy
Solonina I. A., Kiselev M. R., Makaev S. V., Rodnikova M. N. Phase equilibrium in the ternary system water–ethylene glycol–dimethyl sulfoxide // Mendeleev Communications. 2021. Vol. 31. No. 6. pp. 890-892.
RIS
 | 
Cite this
RIS Copy
TY - JOUR
DO - 10.1016/j.mencom.2021.11.041
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.11.041
TI - Phase equilibrium in the ternary system water–ethylene glycol–dimethyl sulfoxide
T2 - Mendeleev Communications
AU - Solonina, Irina Aleksandrovna
AU - Kiselev, Mikhail Romanovich
AU - Makaev, Sergey Vladimirovich
AU - Rodnikova, Margarita Nikolaevna
PY - 2021
DA - 2021/11/08
PB - Mendeleev Communications
SP - 890-892
IS - 6
VL - 31
ER -
BibTex
 | 
Cite this
BibTex (up to 50 authors) Copy
@article{2021_Solonina,
author = {Irina Aleksandrovna Solonina and Mikhail Romanovich Kiselev and Sergey Vladimirovich Makaev and Margarita Nikolaevna Rodnikova},
title = {Phase equilibrium in the ternary system water–ethylene glycol–dimethyl sulfoxide},
journal = {Mendeleev Communications},
year = {2021},
volume = {31},
publisher = {Mendeleev Communications},
month = {Nov},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.11.041},
number = {6},
pages = {890--892},
doi = {10.1016/j.mencom.2021.11.041}
}
MLA
Cite this
MLA Copy
Solonina, Irina Aleksandrovna, et al. “Phase equilibrium in the ternary system water–ethylene glycol–dimethyl sulfoxide.” Mendeleev Communications, vol. 31, no. 6, Nov. 2021, pp. 890-892. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.11.041.

Keywords

cryobiology
dimethyl sulfoxide
ethylene glycol
phase equilibria
supercooled solutions
water

Abstract

The ternary system water–ethylene glycol–dimethyl sulfoxide (H2O–EG–DMSO) was investigated by differential scanning calorimetry in the temperature range of 188–298 K. In the concentration range from ∼10 to ∼50 mol% DMSO, crystallization or glass formation are not observed when the temperature is lowered to 188 K. Significant supercooling of the solution in this composition range is explained by the existence of spatial networks of H2O and EG.

References

4.
Klapshin Y.P., Solonina I.A., Rodnikova M.N., Kiselev M.R., Khoroshilov A.V., Makaev S.V.
Mendeleev Communications, 2020
5.
Phase Diagram for the System Water–Dimethylsulphoxide
RASMUSSEN D.H., MACKENZIE A.P.
Nature, 1968
6.
ASTM Method D-1177-93a, Standard Test Method for Freezing Point of Aqueous Engine Coolant, American Society for Testing and Materials, Philadelphia, PA, 1993.
7.
Solid - liquid phase diagram for ethylene glycol + water
Cordray D.R., Kaplan L.R., Woyciesjes P.M., Kozak T.F.
Fluid Phase Equilibria, 1996
9.
10.1016/j.mencom.2021.11.041_b0045
Zinchenko
Kriobiologiya (Cryobiology), 1986
10.
Solid-liquid phase equilibria in water + ethylene glycol
Ott J.B., Goates J.R., Lamb J.D.
Journal of Chemical Thermodynamics, 1972
11.
Phase Diagram of the Ethylene Glycol–Dimethylsulfoxide System
Solonina I.A., Rodnikova M.N., Kiselev M.R., Khoroshilov A.V., Shirokova E.V.
Russian Journal of Physical Chemistry A, 2018
12.
M. N. Rodnikova, Russ. J. Phys. Chem. A, 1993, 67, 248 (Zh. Fiz. Khim., 1993, 67, 275).
14.
IR Spectroscopy of Solutions of Dimethylsulfoxide in Monoethanolamine
Kononova E.G., Rodnikova M.N., Solonina I.A., Shirokova E.V.
Russian Journal of Physical Chemistry A, 2020
16.
Molecular mobility and the structure of polar liquids
Rodnikova M.N., Samigullin F.M., Solonina I.A., Sirotkin D.A.
Journal of Structural Chemistry, 2014