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Effect of 1-hexene on the propylene polymerization with supported phthalate-free titanium–magnesium catalyst

Alexander Mikhailovich Aladyshev 1
Alexander Mikhailovich Aladyshev
, 
Alla Nisonovna Klyamkina 1
Alla Nisonovna Klyamkina
, 
Polina Mikhailovna Nedorezova 1
Polina Mikhailovna Nedorezova
10.1016/j.mencom.2021.11.037
Published 2021-11-08
Communication , Volume 31, Issue 6, 878-880
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Aladyshev A. M., Klyamkina A. N., Nedorezova P. M. Effect of 1-hexene on the propylene polymerization with supported phthalate-free titanium–magnesium catalyst // Mendeleev Communications. 2021. Vol. 31. No. 6. pp. 878-880.
GOST all authors (up to 50) Copy
Aladyshev A. M., Klyamkina A. N., Nedorezova P. M. Effect of 1-hexene on the propylene polymerization with supported phthalate-free titanium–magnesium catalyst // Mendeleev Communications. 2021. Vol. 31. No. 6. pp. 878-880.
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TY - JOUR
DO - 10.1016/j.mencom.2021.11.037
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.11.037
TI - Effect of 1-hexene on the propylene polymerization with supported phthalate-free titanium–magnesium catalyst
T2 - Mendeleev Communications
AU - Aladyshev, Alexander Mikhailovich
AU - Klyamkina, Alla Nisonovna
AU - Nedorezova, Polina Mikhailovna
PY - 2021
DA - 2021/11/08
PB - Mendeleev Communications
SP - 878-880
IS - 6
VL - 31
ER -
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@article{2021_Aladyshev,
author = {Alexander Mikhailovich Aladyshev and Alla Nisonovna Klyamkina and Polina Mikhailovna Nedorezova},
title = {Effect of 1-hexene on the propylene polymerization with supported phthalate-free titanium–magnesium catalyst},
journal = {Mendeleev Communications},
year = {2021},
volume = {31},
publisher = {Mendeleev Communications},
month = {Nov},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.11.037},
number = {6},
pages = {878--880},
doi = {10.1016/j.mencom.2021.11.037}
}
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Aladyshev, Alexander Mikhailovich, et al. “Effect of 1-hexene on the propylene polymerization with supported phthalate-free titanium–magnesium catalyst.” Mendeleev Communications, vol. 31, no. 6, Nov. 2021, pp. 878-880. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.11.037.

Keywords

1-hexene
copolymerization
liquid propylene
thermophysical and mechanical properties
titanium–magnesium catalyst

Abstract

The polymerization of propylene with small amounts of 1-hexene in the presence of supported titanium–magnesium catalyst containing two internal non-phthalate donors was accomplished. Polypropylene modification with small amounts of 1-hexene affects the thermophysical properties and molecular weight characteristics of the polymers. The activation mechanism of the reaction is described; the introduction of small amounts of 1-hexene causes an increase in activity by a factor of 1.5.

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