Home / Publications / Hydrogenation of nitroarenes on silica-supported copper catalyst

Hydrogenation of nitroarenes on silica-supported copper catalyst

Elena Vladimirovna Shuvalova 1
Elena Vladimirovna Shuvalova
, 
Olga Alekseevna Kirichenko 1
Olga Alekseevna Kirichenko
10.1016/j.mencom.2021.11.036
Published 2021-11-08
Communication , Volume 31, Issue 6, 875-877
12
Share
Cite this
GOST
 | 
Cite this
GOST Copy
Shuvalova E. V., Kirichenko O. A. Hydrogenation of nitroarenes on silica-supported copper catalyst // Mendeleev Communications. 2021. Vol. 31. No. 6. pp. 875-877.
GOST all authors (up to 50) Copy
Shuvalova E. V., Kirichenko O. A. Hydrogenation of nitroarenes on silica-supported copper catalyst // Mendeleev Communications. 2021. Vol. 31. No. 6. pp. 875-877.
RIS
 | 
Cite this
RIS Copy
TY - JOUR
DO - 10.1016/j.mencom.2021.11.036
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.11.036
TI - Hydrogenation of nitroarenes on silica-supported copper catalyst
T2 - Mendeleev Communications
AU - Shuvalova, Elena Vladimirovna
AU - Kirichenko, Olga Alekseevna
PY - 2021
DA - 2021/11/08
PB - Mendeleev Communications
SP - 875-877
IS - 6
VL - 31
ER -
BibTex
 | 
Cite this
BibTex (up to 50 authors) Copy
@article{2021_Shuvalova,
author = {Elena Vladimirovna Shuvalova and Olga Alekseevna Kirichenko},
title = {Hydrogenation of nitroarenes on silica-supported copper catalyst},
journal = {Mendeleev Communications},
year = {2021},
volume = {31},
publisher = {Mendeleev Communications},
month = {Nov},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.11.036},
number = {6},
pages = {875--877},
doi = {10.1016/j.mencom.2021.11.036}
}
MLA
Cite this
MLA Copy
Shuvalova, Elena Vladimirovna, and Olga Alekseevna Kirichenko. “Hydrogenation of nitroarenes on silica-supported copper catalyst.” Mendeleev Communications, vol. 31, no. 6, Nov. 2021, pp. 875-877. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.11.036.

Keywords

anilines
copper catalysts
hydrogen
hydrogenation
nitro group
nitroarenes

Abstract

A 9% Cu/SiO2 catalyst prepared by the deposition– precipitation technique was active in the hydrogenation of substituted nitrobenzenes at 170 °C and 13 atm H2 in a batch reactor. Nitro groups were selectively reduced to NH2 groups except for the case of 5-bromo-1,3-dinitrobenzene. The selectivity of the overall process is somewhat suppressed by inevitable formation of azo compounds and traces of tars due to the reactions of the obtained amines with nitroso intermediates.

References

1.
Review on selective hydrogenation of nitroarene by catalytic, photocatalytic and electrocatalytic reactions
Song J., Huang Z., Pan L., Li K., Zhang X., Wang L., Zou J.
Applied Catalysis B: Environmental, 2018
3.
Reduction of Nitro Compounds Using 3d-Non-Noble Metal Catalysts.
Formenti D., Ferretti F., Scharnagl F.K., Beller M.
Chemical Reviews, 2018
4.
Hydrogenation of Nitrobenzene over a Pd/Al2O3Catalyst - Mechanism and Effect of the Main Operating Conditions
Couto C.S., Madeira L.M., Nunes C.P., Araújo P.
Chemical Engineering and Technology, 2015
5.
Catalytic Hydrogenation of p-Chloronitrobenzene to p-Chloroaniline Mediated by γ-Mo2N
Jaf Z.N., Altarawneh M., Miran H.A., Almatarneh M.H., Jiang Z., Dlugogorski B.Z.
ACS Omega, 2018
6.
Concurrent Hydrogenation of Aromatic and Nitro Groups over Carbon-Supported Ruthenium Catalysts
Tomkins P., Gebauer-Henke E., Leitner W., Müller T.E.
ACS Catalysis, 2014
7.
Water-soluble gold nanoparticles: recyclable catalysts for the reduction of aromatic nitro compounds in water
Monti G.A., Correa N.M., Falcone R.D., Silbestri G.F., Moyano F.
RSC Advances, 2020
8.
Nuzhdin A.L., Bukhtiyarova G.A., Lin T., Gerasimov E.Y., Bukhtiyarov V.I.
Mendeleev Communications, 2019
10.
10.1016/j.mencom.2021.11.036_b0050
Litvin
Ross. Khim. Zh., 2000
11.
Nickel catalysis for hydrogenation of p-dinitrobenzene to p-phenylenediamine
Shuvalova E.V., Kirichenko O.A., Kustov L.M.
Russian Chemical Bulletin, 2017
12.
Nitrobenzene hydrogenation over Ni/TiO2 catalyst in vapour phase at atmospheric pressure: influence of preparation method
Varkolu M., Velpula V., Pochamoni R., Muppala A.R., Burri D.R., Kamaraju S.R.
Applied Petrochemical Research, 2015
14.
Synthesis of Supported Planar Iron Oxide Nanoparticles and Their Chemo- and Stereoselectivity for Hydrogenation of Alkynes
Tejeda-Serrano M., Cabrero-Antonino J.R., Mainar-Ruiz V., López-Haro M., Hernández-Garrido J.C., Calvino J.J., Leyva-Pérez A., Corma A.
ACS Catalysis, 2017
15.
Isolated Iron Single-Atomic Site-Catalyzed Chemoselective Transfer Hydrogenation of Nitroarenes to Arylamines
Cheong W., Yang W., Zhang J., Li Y., Zhao D., Liu S., Wu K., Liu Q., Zhang C., Wang D., Peng Q., Chen C., Li Y.
ACS applied materials & interfaces, 2019
16.
Selective Liquid Phase Hydrogenation of Aromatic Nitro Compounds in the Presence of Fe–Cu Nanoparticles
Shesterkina A.A., Strekalova A.A., Kustov L.M.
Russian Journal of Physical Chemistry A, 2020
18.
Copper-Based Intermetallic Electride Catalyst for Chemoselective Hydrogenation Reactions.
Ye T., Lu Y., Li J., Nakao T., Yang H., Tada T., Kitano M., Hosono H.
Journal of the American Chemical Society, 2017
20.
Catalytic Activity of Cu and Cu–Fe Hydrosilicates in Hydrogenation with Molecular Hydrogen
Kirichenko O.A., Shuvalova E.V., Strekalova A.A., Davshan N.A., Kapustin G.I., Nissenbaum V.D.
Russian Journal of Physical Chemistry A, 2018
22.
Interfacing with silica boosts the catalysis of copper
Xu C., Chen G., Zhao Y., Liu P., Duan X., Gu L., Fu G., Yuan Y., Zheng N.
Nature Communications, 2018
23.
The reduction behaviour of silica-supported copper catalysts prepared by deposition-precipitation
Van Der Grift C.J., Wielers A.F., Mulder A., Geus J.W.
Thermochimica Acta, 1990