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Novel capto-dative (Z,E)-2-(alkylthio)alk-2-en-4-ynals: synthesis and heterocyclization

Victoria Germanovna Fedoseeva 1
Victoria Germanovna Fedoseeva
, 
Ekaterina Aleksandrovna Verochkina 1
Ekaterina Aleksandrovna Verochkina
, 
Lyudmila Ivanovna Larina 1
Lyudmila Ivanovna Larina
, 
Evgenii Vladimirovich Kondrashov 1
Evgenii Vladimirovich Kondrashov
, 
Igor Borisovich Rosentsveig 1
Igor Borisovich Rosentsveig
, 
Nadezhda Viktorovna Vchislo 1
Nadezhda Viktorovna Vchislo
10.1016/j.mencom.2021.11.029
Published 2021-11-08
Communication , Volume 31, Issue 6, 856-858
6
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Fedoseeva V. G. et al. Novel capto-dative (Z,E)-2-(alkylthio)alk-2-en-4-ynals: synthesis and heterocyclization // Mendeleev Communications. 2021. Vol. 31. No. 6. pp. 856-858.
GOST all authors (up to 50) Copy
Fedoseeva V. G., Verochkina E. A., Larina L. I., Kondrashov E. V., Rosentsveig I. B., Vchislo N. V. Novel capto-dative (Z,E)-2-(alkylthio)alk-2-en-4-ynals: synthesis and heterocyclization // Mendeleev Communications. 2021. Vol. 31. No. 6. pp. 856-858.
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TY - JOUR
DO - 10.1016/j.mencom.2021.11.029
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.11.029
TI - Novel capto-dative (Z,E)-2-(alkylthio)alk-2-en-4-ynals: synthesis and heterocyclization
T2 - Mendeleev Communications
AU - Fedoseeva, Victoria Germanovna
AU - Verochkina, Ekaterina Aleksandrovna
AU - Larina, Lyudmila Ivanovna
AU - Kondrashov, Evgenii Vladimirovich
AU - Rosentsveig, Igor Borisovich
AU - Vchislo, Nadezhda Viktorovna
PY - 2021
DA - 2021/11/08
PB - Mendeleev Communications
SP - 856-858
IS - 6
VL - 31
ER -
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@article{2021_Fedoseeva,
author = {Victoria Germanovna Fedoseeva and Ekaterina Aleksandrovna Verochkina and Lyudmila Ivanovna Larina and Evgenii Vladimirovich Kondrashov and Igor Borisovich Rosentsveig and Nadezhda Viktorovna Vchislo},
title = {Novel capto-dative (Z,E)-2-(alkylthio)alk-2-en-4-ynals: synthesis and heterocyclization},
journal = {Mendeleev Communications},
year = {2021},
volume = {31},
publisher = {Mendeleev Communications},
month = {Nov},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.11.029},
number = {6},
pages = {856--858},
doi = {10.1016/j.mencom.2021.11.029}
}
MLA
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Fedoseeva, Victoria Germanovna, et al. “Novel capto-dative (Z,E)-2-(alkylthio)alk-2-en-4-ynals: synthesis and heterocyclization.” Mendeleev Communications, vol. 31, no. 6, Nov. 2021, pp. 856-858. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.11.029.

Keywords

aldol condensation
enynals
heterocyclization
imidazolidines
organogermanium compounds
oxazoles
Α-enals

Abstract

An efficient synthesis of new (Z,E)-2-(alkylthio)alk-2-en-4-ynals by aldol condensation reaction of ynals with (alkylthio)-acetaldehydes using NaOH/DMF system has been developed.The reaction of these products with N,N-diphenylethylene-diamine and p-tosylmethyl isocyanide proceeds at the carbonyl group to form the corresponding imidazolidine and oxazole derivatives.

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