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Significant impact of lanthanide contraction on the structure of the phenanthroline complexes

Pavel Sergeevich Lemport 1
Pavel Sergeevich Lemport
, 
Mariia Valer'evna Evsiunina 1
Mariia Valer'evna Evsiunina
,  , 
Kseniya Leonidovna Isakovskaya 2, 3
Kseniya Leonidovna Isakovskaya
, 
Victor Nikolaevich Khrustalev 4, 5
Victor Nikolaevich Khrustalev
, 
Valentine Stanislavovich Petrov 1
Valentine Stanislavovich Petrov
, 
Anton Sergeyevich Pozdeev 1
Anton Sergeyevich Pozdeev
,  , 
Yuri Aleksandrovich Ustynyuk 1
Yuri Aleksandrovich Ustynyuk
, 
Valentin Georgievich Nenajdenko 1
Valentin Georgievich Nenajdenko
10.1016/j.mencom.2021.11.028
Published 2021-11-08
Communication , Volume 31, Issue 6, 853-855
29
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Lemport P. S. et al. Significant impact of lanthanide contraction on the structure of the phenanthroline complexes // Mendeleev Communications. 2021. Vol. 31. No. 6. pp. 853-855.
GOST all authors (up to 50) Copy
Lemport P. S., Evsiunina M. V., Nelyubina Y. V., Isakovskaya K. L., Khrustalev V. N., Petrov V. S., Pozdeev A. S., Matveev P. I., Ustynyuk Y. A., Nenajdenko V. G. Significant impact of lanthanide contraction on the structure of the phenanthroline complexes // Mendeleev Communications. 2021. Vol. 31. No. 6. pp. 853-855.
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TY - JOUR
DO - 10.1016/j.mencom.2021.11.028
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.11.028
TI - Significant impact of lanthanide contraction on the structure of the phenanthroline complexes
T2 - Mendeleev Communications
AU - Lemport, Pavel Sergeevich
AU - Evsiunina, Mariia Valer'evna
AU - Nelyubina, Yulia Vladimirovna
AU - Isakovskaya, Kseniya Leonidovna
AU - Khrustalev, Victor Nikolaevich
AU - Petrov, Valentine Stanislavovich
AU - Pozdeev, Anton Sergeyevich
AU - Matveev, Petr Igorevich
AU - Ustynyuk, Yuri Aleksandrovich
AU - Nenajdenko, Valentin Georgievich
PY - 2021
DA - 2021/11/08
PB - Mendeleev Communications
SP - 853-855
IS - 6
VL - 31
ER -
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@article{2021_Lemport,
author = {Pavel Sergeevich Lemport and Mariia Valer'evna Evsiunina and Yulia Vladimirovna Nelyubina and Kseniya Leonidovna Isakovskaya and Victor Nikolaevich Khrustalev and Valentine Stanislavovich Petrov and Anton Sergeyevich Pozdeev and Petr Igorevich Matveev and Yuri Aleksandrovich Ustynyuk and Valentin Georgievich Nenajdenko},
title = {Significant impact of lanthanide contraction on the structure of the phenanthroline complexes},
journal = {Mendeleev Communications},
year = {2021},
volume = {31},
publisher = {Mendeleev Communications},
month = {Nov},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.11.028},
number = {6},
pages = {853--855},
doi = {10.1016/j.mencom.2021.11.028}
}
MLA
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Lemport, Pavel Sergeevich, et al. “Significant impact of lanthanide contraction on the structure of the phenanthroline complexes.” Mendeleev Communications, vol. 31, no. 6, Nov. 2021, pp. 853-855. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.11.028.

Keywords

complex
coordination number
lanthanide
lutetium complexes
phenanthrolinediamide
polydentate ligand
X-ray

Abstract

The structure of La, Nd, Eu and Lu complexes with N,N,N',N'-tetrabutyl-1,10-phenanthroline-2,9-dicarbox- amide ligand was examined using X-ray diffraction analysis. Due to the effect of lanthanide contraction, lutetium forms unique type of complex having the coordination number 9 in contrast to other 10-coordinated lanthanides.

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