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Tetrylenes based on polydentate sulfur-containing ligands

Andrey Igorevich Fedulin 1
Andrey Igorevich Fedulin
, 
Yurii Fedorovich Oprunenko 1
Yurii Fedorovich Oprunenko
, 
Sergey Sergeevich Karlov 1
Sergey Sergeevich Karlov
, 
Galina Stepanovna Zaitseva 1
Galina Stepanovna Zaitseva
, 
Kirill Vladimirovich Zaitsev 1, 2
Kirill Vladimirovich Zaitsev
10.1016/j.mencom.2021.11.027
Published 2021-11-08
Communication , Volume 31, Issue 6, 850-852
3
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Fedulin A. I. et al. Tetrylenes based on polydentate sulfur-containing ligands // Mendeleev Communications. 2021. Vol. 31. No. 6. pp. 850-852.
GOST all authors (up to 50) Copy
Fedulin A. I., Oprunenko Y. F., Karlov S. S., Zaitseva G. S., Zaitsev K. V. Tetrylenes based on polydentate sulfur-containing ligands // Mendeleev Communications. 2021. Vol. 31. No. 6. pp. 850-852.
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TY - JOUR
DO - 10.1016/j.mencom.2021.11.027
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.11.027
TI - Tetrylenes based on polydentate sulfur-containing ligands
T2 - Mendeleev Communications
AU - Fedulin, Andrey Igorevich
AU - Oprunenko, Yurii Fedorovich
AU - Karlov, Sergey Sergeevich
AU - Zaitseva, Galina Stepanovna
AU - Zaitsev, Kirill Vladimirovich
PY - 2021
DA - 2021/11/08
PB - Mendeleev Communications
SP - 850-852
IS - 6
VL - 31
ER -
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@article{2021_Fedulin,
author = {Andrey Igorevich Fedulin and Yurii Fedorovich Oprunenko and Sergey Sergeevich Karlov and Galina Stepanovna Zaitseva and Kirill Vladimirovich Zaitsev},
title = {Tetrylenes based on polydentate sulfur-containing ligands},
journal = {Mendeleev Communications},
year = {2021},
volume = {31},
publisher = {Mendeleev Communications},
month = {Nov},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.11.027},
number = {6},
pages = {850--852},
doi = {10.1016/j.mencom.2021.11.027}
}
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Fedulin, Andrey Igorevich, et al. “Tetrylenes based on polydentate sulfur-containing ligands.” Mendeleev Communications, vol. 31, no. 6, Nov. 2021, pp. 850-852. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.11.027.

Keywords

germylenes
oligomerization
organosulfur compounds
polydentate ligands
ring-opening
stannylenes
tetrylenes
thiiranes

Abstract

Polydentate SNO-coordinating proligands were obtained by addition of thioacetic acid to conjugated alkene, or ring-opening of thiiranes with organolithium compounds as the key stages. These SNO- and known SNS- and SOS- coordinating proligands were used for the synthesis of tetrylenes by the reaction with Lappert’s tetrylenes E[N(SiMe3)2]2 (E = Ge, Sn), giving polymeric, monomeric or dimeric species depending on the type of the ligand. The structure of stannylenes in solution was analysed by 119Sn NMR spectroscopy.

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