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Methylaluminum complexes based on tridentate 2,6-bis(mercaptoalkyl)pyridine SNS-ligands

Andrey Igorevich Fedulin 1
Andrey Igorevich Fedulin
, 
Andrei Viktorovich Churakov 2
Andrei Viktorovich Churakov
, 
Kirill Vladimirovich Zaitsev 1, 3
Kirill Vladimirovich Zaitsev
10.1016/j.mencom.2021.11.026
Published 2021-11-08
Communication , Volume 31, Issue 6, 847-849
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Fedulin A. I., Churakov A. V., Zaitsev K. V. Methylaluminum complexes based on tridentate 2,6-bis(mercaptoalkyl)pyridine SNS-ligands // Mendeleev Communications. 2021. Vol. 31. No. 6. pp. 847-849.
GOST all authors (up to 50) Copy
Fedulin A. I., Churakov A. V., Zaitsev K. V. Methylaluminum complexes based on tridentate 2,6-bis(mercaptoalkyl)pyridine SNS-ligands // Mendeleev Communications. 2021. Vol. 31. No. 6. pp. 847-849.
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TY - JOUR
DO - 10.1016/j.mencom.2021.11.026
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.11.026
TI - Methylaluminum complexes based on tridentate 2,6-bis(mercaptoalkyl)pyridine SNS-ligands
T2 - Mendeleev Communications
AU - Fedulin, Andrey Igorevich
AU - Churakov, Andrei Viktorovich
AU - Zaitsev, Kirill Vladimirovich
PY - 2021
DA - 2021/11/08
PB - Mendeleev Communications
SP - 847-849
IS - 6
VL - 31
ER -
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@article{2021_Fedulin,
author = {Andrey Igorevich Fedulin and Andrei Viktorovich Churakov and Kirill Vladimirovich Zaitsev},
title = {Methylaluminum complexes based on tridentate 2,6-bis(mercaptoalkyl)pyridine SNS-ligands},
journal = {Mendeleev Communications},
year = {2021},
volume = {31},
publisher = {Mendeleev Communications},
month = {Nov},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.11.026},
number = {6},
pages = {847--849},
doi = {10.1016/j.mencom.2021.11.026}
}
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Fedulin, Andrey Igorevich, et al. “Methylaluminum complexes based on tridentate 2,6-bis(mercaptoalkyl)pyridine SNS-ligands.” Mendeleev Communications, vol. 31, no. 6, Nov. 2021, pp. 847-849. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.11.026.

Keywords

methyl aluminum complexes
organoaluminum compounds
ring-opening of thiiranes
ring-opening polymerization of lactones
SNS-polydentate ligands
thiiranes

Abstract

New SNS-ligands were obtained by consequent ring-opening of substituted thiiranes by lithiated 2,6-lutidine, mono- functionalized SN-ligands having been isolated as the intermediate compounds. The molecular structure of ligand 2,6-Py(CH2CH2CBn2SH)2 was elucidated by XRD analysis.The reaction of AlMe3 with SNS-ligands afforded monomeric methyl aluminum complexes which have been tested in ring- opening polymerization of ε caprolactone in bulk.

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