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Effect of micelles on pKa* of acridine: a spectroscopic study

Alina Olegovna Naumova 1
Alina Olegovna Naumova
Andrey K Afanasyev 1
Andrey K Afanasyev
Pavel Valentinovich Melnikov 1
Pavel Valentinovich Melnikov
Nikolay Konkordievich Zaitsev 1
Nikolay Konkordievich Zaitsev
Published 2021-11-08
CommunicationVolume 31, Issue 6, 833-835
3
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Naumova A. O. et al. Effect of micelles on pKa* of acridine: a spectroscopic study // Mendeleev Communications. 2021. Vol. 31. No. 6. pp. 833-835.
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Naumova A. O., Afanasyev A. K., Melnikov P. V., Zaitsev N. K. Effect of micelles on pKa* of acridine: a spectroscopic study // Mendeleev Communications. 2021. Vol. 31. No. 6. pp. 833-835.
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TY - JOUR
DO - 10.1016/j.mencom.2021.11.021
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.11.021
TI - Effect of micelles on pKa* of acridine: a spectroscopic study
T2 - Mendeleev Communications
AU - Naumova, Alina Olegovna
AU - Afanasyev, Andrey K
AU - Melnikov, Pavel Valentinovich
AU - Zaitsev, Nikolay Konkordievich
PY - 2021
DA - 2021/11/08
PB - Mendeleev Communications
SP - 833-835
IS - 6
VL - 31
ER -
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@article{2021_Naumova,
author = {Alina Olegovna Naumova and Andrey K Afanasyev and Pavel Valentinovich Melnikov and Nikolay Konkordievich Zaitsev},
title = {Effect of micelles on pKa* of acridine: a spectroscopic study},
journal = {Mendeleev Communications},
year = {2021},
volume = {31},
publisher = {Mendeleev Communications},
month = {Nov},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.11.021},
number = {6},
pages = {833--835},
doi = {10.1016/j.mencom.2021.11.021}
}
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Naumova, Alina Olegovna, et al. “Effect of micelles on pKa* of acridine: a spectroscopic study.” Mendeleev Communications, vol. 31, no. 6, Nov. 2021, pp. 833-835. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.11.021.

Keywords

acid–base reaction
excited state
fluorescence
micelles
photobase
photoinduced proton transfer
protonation
shift in equilibrium
surfactants

Abstract

The effect of anionic, nonionic and cationic surfactants on the protonation reaction of acridine in an excited state has been studied. In the case of sodium decyl sulfate and sodium dodecyl sulfate, the observed shift in pK * to a more alkaline region was +0.6 and +0.9 units (from 9.9 to 10.5 and 10.8 respectively), which corresponds to a decrease in the Gibbs free energy by 3.5 and 5.0 kJ mol–1.

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