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Oxidation step in the preparation of benzocamalexin: The crystallographic evidence

Yordan Stremski 1
Yordan Stremski
, 
Anife Ismailova Ahmedova 2
Anife Ismailova Ahmedova
, 
Anna Dolega 3
Anna Dolega
, 
Stela Statkova-Abeghe 1
Stela Statkova-Abeghe
, 
Desislava Kirkova 4
Desislava Kirkova
10.1016/j.mencom.2021.11.018
Published 2021-11-08
Communication , Volume 31, Issue 6, 824-826
6
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Stremski Y. et al. Oxidation step in the preparation of benzocamalexin: The crystallographic evidence // Mendeleev Communications. 2021. Vol. 31. No. 6. pp. 824-826.
GOST all authors (up to 50) Copy
Stremski Y., Ahmedova A. I., Dolega A., Statkova-Abeghe S., Kirkova D. Oxidation step in the preparation of benzocamalexin: The crystallographic evidence // Mendeleev Communications. 2021. Vol. 31. No. 6. pp. 824-826.
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TY - JOUR
DO - 10.1016/j.mencom.2021.11.018
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.11.018
TI - Oxidation step in the preparation of benzocamalexin: The crystallographic evidence
T2 - Mendeleev Communications
AU - Stremski, Yordan
AU - Ahmedova, Anife Ismailova
AU - Dolega, Anna
AU - Statkova-Abeghe, Stela
AU - Kirkova, Desislava
PY - 2021
DA - 2021/11/08
PB - Mendeleev Communications
SP - 824-826
IS - 6
VL - 31
ER -
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@article{2021_Stremski,
author = {Yordan Stremski and Anife Ismailova Ahmedova and Anna Dolega and Stela Statkova-Abeghe and Desislava Kirkova},
title = {Oxidation step in the preparation of benzocamalexin: The crystallographic evidence},
journal = {Mendeleev Communications},
year = {2021},
volume = {31},
publisher = {Mendeleev Communications},
month = {Nov},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.11.018},
number = {6},
pages = {824--826},
doi = {10.1016/j.mencom.2021.11.018}
}
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MLA Copy
Stremski, Yordan, et al. “Oxidation step in the preparation of benzocamalexin: The crystallographic evidence.” Mendeleev Communications, vol. 31, no. 6, Nov. 2021, pp. 824-826. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.11.018.

Keywords

o-chloranil
benzocamalexin
crystal structures
phytoalexins
α-amidoalkylation

Abstract

The study of oxidation step in the preparation of benzocamalexin by the α-amidoalkylation–oxidation sequence revealed the formation of perchloro-1,2-phenylene dibenzoate as the product of transformation of tetrachloro- 1,2-benzoquinone applied as the oxidant. The structures of benzocamalexin and perchloro-1,2-phenylene dibenzoate were confirmed by X-ray diffraction analysis. The extraction step in the final isolation of benzocamalexin is supposed to be crucial for the complete transformation of mono- and di- acylated perchloropyrocatechol.

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