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Dinuclear ReI complex based on 1,2,4,5-tetrakis(diphenylphosphino)- pyridine: synthesis and luminescence properties

Maxim Yuryevich Petyuk 1
Maxim Yuryevich Petyuk
, 
Irina Yur'evna Bagryanskaya 2
Irina Yur'evna Bagryanskaya
, 
Oleg Ivanovich Artyushin 3
Oleg Ivanovich Artyushin
,  , 
Alexandr Viktorovich Artem’ev 1
Alexandr Viktorovich Artem’ev
10.1016/j.mencom.2021.11.013
Published 2021-11-08
Communication , Volume 31, Issue 6, 810-812
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Petyuk M. Y. et al. Dinuclear ReI complex based on 1,2,4,5-tetrakis(diphenylphosphino)- pyridine: synthesis and luminescence properties // Mendeleev Communications. 2021. Vol. 31. No. 6. pp. 810-812.
GOST all authors (up to 50) Copy
Petyuk M. Y., Bagryanskaya I. Y., Artyushin O. I., Brel V. K., Artem’ev A. V. Dinuclear ReI complex based on 1,2,4,5-tetrakis(diphenylphosphino)- pyridine: synthesis and luminescence properties // Mendeleev Communications. 2021. Vol. 31. No. 6. pp. 810-812.
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TY - JOUR
DO - 10.1016/j.mencom.2021.11.013
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.11.013
TI - Dinuclear ReI complex based on 1,2,4,5-tetrakis(diphenylphosphino)- pyridine: synthesis and luminescence properties
T2 - Mendeleev Communications
AU - Petyuk, Maxim Yuryevich
AU - Bagryanskaya, Irina Yur'evna
AU - Artyushin, Oleg Ivanovich
AU - Brel, Valery Kuzmich
AU - Artem’ev, Alexandr Viktorovich
PY - 2021
DA - 2021/11/08
PB - Mendeleev Communications
SP - 810-812
IS - 6
VL - 31
ER -
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@article{2021_Petyuk,
author = {Maxim Yuryevich Petyuk and Irina Yur'evna Bagryanskaya and Oleg Ivanovich Artyushin and Valery Kuzmich Brel and Alexandr Viktorovich Artem’ev},
title = {Dinuclear ReI complex based on 1,2,4,5-tetrakis(diphenylphosphino)- pyridine: synthesis and luminescence properties},
journal = {Mendeleev Communications},
year = {2021},
volume = {31},
publisher = {Mendeleev Communications},
month = {Nov},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.11.013},
number = {6},
pages = {810--812},
doi = {10.1016/j.mencom.2021.11.013}
}
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Petyuk, Maxim Yuryevich, et al. “Dinuclear ReI complex based on 1,2,4,5-tetrakis(diphenylphosphino)- pyridine: synthesis and luminescence properties.” Mendeleev Communications, vol. 31, no. 6, Nov. 2021, pp. 810-812. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.11.013.

Keywords

halocarbonyl complexes
phosphorescence
rhenium (I)
synthesis
tetraphosphine ligands

Abstract

The reaction of 1,2,4,5-tetrakis(diphenylphosphino)pyridine (L) with Re(CO)5Br (in a molar ratio of 1:2) leads to the bis-chelated complex [Re2(CO)6(L)Br2] in 95% yield. At ambient temperature, the solid complex exhibits green phosphorescence (λmax = 535 nm) with a quantum yield of 12% and a lifetime of 90 μs.

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