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Luminescent [Cu8I8L6] wheel and [Cu2I2L3] cage assembled from CuI and 3,6-bis(diphenylphosphino)pyridazine

Maxim Igorevich Rogovoy 1
Maxim Igorevich Rogovoy
, 
Mariana Ivanovna Rakhmanova 1
Mariana Ivanovna Rakhmanova
, 
Taisiya Sergeevna Sukhikh 1
Taisiya Sergeevna Sukhikh
, 
Alexandr Viktorovich Artem’ev 1
Alexandr Viktorovich Artem’ev
10.1016/j.mencom.2021.11.011
Published 2021-11-08
Communication , Volume 31, Issue 6, 804-806
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Rogovoy M. I. et al. Luminescent [Cu8I8L6] wheel and [Cu2I2L3] cage assembled from CuI and 3,6-bis(diphenylphosphino)pyridazine // Mendeleev Communications. 2021. Vol. 31. No. 6. pp. 804-806.
GOST all authors (up to 50) Copy
Rogovoy M. I., Rakhmanova M. I., Sukhikh T. S., Artem’ev A. V. Luminescent [Cu8I8L6] wheel and [Cu2I2L3] cage assembled from CuI and 3,6-bis(diphenylphosphino)pyridazine // Mendeleev Communications. 2021. Vol. 31. No. 6. pp. 804-806.
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TY - JOUR
DO - 10.1016/j.mencom.2021.11.011
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.11.011
TI - Luminescent [Cu8I8L6] wheel and [Cu2I2L3] cage assembled from CuI and 3,6-bis(diphenylphosphino)pyridazine
T2 - Mendeleev Communications
AU - Rogovoy, Maxim Igorevich
AU - Rakhmanova, Mariana Ivanovna
AU - Sukhikh, Taisiya Sergeevna
AU - Artem’ev, Alexandr Viktorovich
PY - 2021
DA - 2021/11/08
PB - Mendeleev Communications
SP - 804-806
IS - 6
VL - 31
ER -
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@article{2021_Rogovoy,
author = {Maxim Igorevich Rogovoy and Mariana Ivanovna Rakhmanova and Taisiya Sergeevna Sukhikh and Alexandr Viktorovich Artem’ev},
title = {Luminescent [Cu8I8L6] wheel and [Cu2I2L3] cage assembled from CuI and 3,6-bis(diphenylphosphino)pyridazine},
journal = {Mendeleev Communications},
year = {2021},
volume = {31},
publisher = {Mendeleev Communications},
month = {Nov},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.11.011},
number = {6},
pages = {804--806},
doi = {10.1016/j.mencom.2021.11.011}
}
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Rogovoy, Maxim Igorevich, et al. “Luminescent [Cu8I8L6] wheel and [Cu2I2L3] cage assembled from CuI and 3,6-bis(diphenylphosphino)pyridazine.” Mendeleev Communications, vol. 31, no. 6, Nov. 2021, pp. 804-806. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.11.011.

Keywords

3,6-bis(diphenylphosphino)pyridazine
coppercomplexes
crystal structure
thermochromic luminescence
wheel-shaped and cage-like complexes

Abstract

The reaction of CuI and 3,6-bis(diphenylphosphino)pyridazine (dppz) in MeCN leads to the wheel-shaped complex [Cu8I8(dppz)6], assembled from four [Cu2I2] units and six dppz ligands. This complex exhibits thermochromic luminescence with emission colors ranging from red (300 K) to deep red (77 K). When carried out in the presence of PPh3, the reaction of CuI with dppz gives a non-emissive cage-like complex [Cu2I2(dppz)3], in which two CuI units are P,P′-bridged by three dppz ligands.

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