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Synthesis and properties of novel energetic (cyano-NNO-azoxy)furazans

Nikita E Leonov 1
Nikita E Leonov
, 
Fedor Mikhailovich Sidorov 1, 2
Fedor Mikhailovich Sidorov
,  , 
Aleksandr Mikhailovich Churakov 1
Aleksandr Mikhailovich Churakov
, 
Yurii Andreevich Strelenko 1
Yurii Andreevich Strelenko
, 
Alevtina Nikolaevna Pivkina 3
Alevtina Nikolaevna Pivkina
, 
Ivan Vladimirovich Fedyanin 4, 5
Ivan Vladimirovich Fedyanin
,  , 
Tatiana Sergeevna Kon'kova 3
Tatiana Sergeevna Kon'kova
, 
Yurii Nikolaevich Matyushin 3
Yurii Nikolaevich Matyushin
, 
Vladimir Alexandrovich Tartakovsky 1
Vladimir Alexandrovich Tartakovsky
10.1016/j.mencom.2021.11.007
Published 2021-11-08
Communication , Volume 31, Issue 6, 792-794
11
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Leonov N. E. et al. Synthesis and properties of novel energetic (cyano-NNO-azoxy)furazans // Mendeleev Communications. 2021. Vol. 31. No. 6. pp. 792-794.
GOST all authors (up to 50) Copy
Leonov N. E., Sidorov F. M., Klenov M. S., Churakov A. M., Strelenko Y. A., Pivkina A. N., Fedyanin I. V., Lempert D. B., Kon'kova T. S., Matyushin Y. N., Tartakovsky V. A. Synthesis and properties of novel energetic (cyano-NNO-azoxy)furazans // Mendeleev Communications. 2021. Vol. 31. No. 6. pp. 792-794.
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TY - JOUR
DO - 10.1016/j.mencom.2021.11.007
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.11.007
TI - Synthesis and properties of novel energetic (cyano-NNO-azoxy)furazans
T2 - Mendeleev Communications
AU - Leonov, Nikita E
AU - Sidorov, Fedor Mikhailovich
AU - Klenov, Michael Sergeevich
AU - Churakov, Aleksandr Mikhailovich
AU - Strelenko, Yurii Andreevich
AU - Pivkina, Alevtina Nikolaevna
AU - Fedyanin, Ivan Vladimirovich
AU - Lempert, David Borisovich
AU - Kon'kova, Tatiana Sergeevna
AU - Matyushin, Yurii Nikolaevich
AU - Tartakovsky, Vladimir Alexandrovich
PY - 2021
DA - 2021/11/08
PB - Mendeleev Communications
SP - 792-794
IS - 6
VL - 31
ER -
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@article{2021_Leonov,
author = {Nikita E Leonov and Fedor Mikhailovich Sidorov and Michael Sergeevich Klenov and Aleksandr Mikhailovich Churakov and Yurii Andreevich Strelenko and Alevtina Nikolaevna Pivkina and Ivan Vladimirovich Fedyanin and David Borisovich Lempert and Tatiana Sergeevna Kon'kova and Yurii Nikolaevich Matyushin and Vladimir Alexandrovich Tartakovsky},
title = {Synthesis and properties of novel energetic (cyano-NNO-azoxy)furazans},
journal = {Mendeleev Communications},
year = {2021},
volume = {31},
publisher = {Mendeleev Communications},
month = {Nov},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.11.007},
number = {6},
pages = {792--794},
doi = {10.1016/j.mencom.2021.11.007}
}
MLA
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MLA Copy
Leonov, Nikita E., et al. “Synthesis and properties of novel energetic (cyano-NNO-azoxy)furazans.” Mendeleev Communications, vol. 31, no. 6, Nov. 2021, pp. 792-794. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.11.007.

Keywords

azoxy compounds
combustion calorimetry
cyano compounds
differential scanning calorimetry
enthalpy of formation
furazans
X-ray diffraction analysis

Abstract

Three novel energetic furazans with a cyano-NNO-azoxy group were synthesized using cyanamide and 2,2,2-tri- fluoro-N-(4-nitrosofurazan-3-yl)acetamide as the starting compounds. (Cyano-NNO-azoxy)furazans obtained display high experimental enthalpies of formation (+742 to +1073 kcal kg−1), good thermal stability (Tonset = 193–222 °C) and moderate mechanical sensitivity. These compounds may be of interest as energetic fillers in solid fuels for ramjet engines and in solid composite propellants.

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