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Novel organic magnet derived from pyrazine-fused furazans

Victor Ivanovich Ovcharenko 1, 2
Victor Ivanovich Ovcharenko
, 
Aleksei Borisovich Sheremetev 1
Aleksei Borisovich Sheremetev
, 
Kirill Vladimirovich Strizhenko 1
Kirill Vladimirovich Strizhenko
, 
Sergei Viktorovich Fokin 2
Sergei Viktorovich Fokin
, 
Galina Vladislavovna Romanenko 2
Galina Vladislavovna Romanenko
, 
Artem Stepanovich Bogomyakov 1, 2
Artem Stepanovich Bogomyakov
, 
Vitaly A Morozov 2
Vitaly A Morozov
, 
Mikhail Aleksandrovich Syroeshkin 1
Mikhail Aleksandrovich Syroeshkin
, 
Anna Yaroslavovna Kozmenkova 1
Anna Yaroslavovna Kozmenkova
, 
Andrei Vitalievich Lalov 1
Andrei Vitalievich Lalov
, 
Mikhail Petrovich Egorov 1
Mikhail Petrovich Egorov
10.1016/j.mencom.2021.11.005
Published 2021-11-08
Communication , Volume 31, Issue 6, 784-788
20
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Ovcharenko V. I. et al. Novel organic magnet derived from pyrazine-fused furazans // Mendeleev Communications. 2021. Vol. 31. No. 6. pp. 784-788.
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Ovcharenko V. I., Sheremetev A. B., Strizhenko K. V., Fokin S. V., Romanenko G. V., Bogomyakov A. S., Morozov V. A., Syroeshkin M. A., Kozmenkova A. Y., Lalov A. V., Egorov M. P. Novel organic magnet derived from pyrazine-fused furazans // Mendeleev Communications. 2021. Vol. 31. No. 6. pp. 784-788.
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TY - JOUR
DO - 10.1016/j.mencom.2021.11.005
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.11.005
TI - Novel organic magnet derived from pyrazine-fused furazans
T2 - Mendeleev Communications
AU - Ovcharenko, Victor Ivanovich
AU - Sheremetev, Aleksei Borisovich
AU - Strizhenko, Kirill Vladimirovich
AU - Fokin, Sergei Viktorovich
AU - Romanenko, Galina Vladislavovna
AU - Bogomyakov, Artem Stepanovich
AU - Morozov, Vitaly A
AU - Syroeshkin, Mikhail Aleksandrovich
AU - Kozmenkova, Anna Yaroslavovna
AU - Lalov, Andrei Vitalievich
AU - Egorov, Mikhail Petrovich
PY - 2021
DA - 2021/11/08
PB - Mendeleev Communications
SP - 784-788
IS - 6
VL - 31
ER -
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@article{2021_Ovcharenko,
author = {Victor Ivanovich Ovcharenko and Aleksei Borisovich Sheremetev and Kirill Vladimirovich Strizhenko and Sergei Viktorovich Fokin and Galina Vladislavovna Romanenko and Artem Stepanovich Bogomyakov and Vitaly A Morozov and Mikhail Aleksandrovich Syroeshkin and Anna Yaroslavovna Kozmenkova and Andrei Vitalievich Lalov and Mikhail Petrovich Egorov},
title = {Novel organic magnet derived from pyrazine-fused furazans},
journal = {Mendeleev Communications},
year = {2021},
volume = {31},
publisher = {Mendeleev Communications},
month = {Nov},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.11.005},
number = {6},
pages = {784--788},
doi = {10.1016/j.mencom.2021.11.005}
}
MLA
Cite this
MLA Copy
Ovcharenko, Victor Ivanovich, et al. “Novel organic magnet derived from pyrazine-fused furazans.” Mendeleev Communications, vol. 31, no. 6, Nov. 2021, pp. 784-788. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.11.005.
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Keywords

ammonium
bis(furazano)pyrazine
McConnell’s exchange model
molecular magnet
potassium
rubidium
sodium
stable radical

Abstract

The first organic magnet based on a high-nitrogen framework of pyrazine-fused furazans Na(L•−)(H2O)3 was found. A quantum-chemical study of M(L•−)(H2O)n, where M = Li, Na, K, Rb, NH4, revealed that exchange coupling energy between the neighboring radical anions proved highly sensitive to the motion of one L•− relative to another.

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