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Hayashi ligand-based rhodium complex in carbon monoxide and molecular hydrogen-assisted reductive amination

, 
Denis Alexandrovich Chusov 1, 2
Denis Alexandrovich Chusov
10.1016/j.mencom.2021.11.004
Published 2021-11-08
Communication , Volume 31, Issue 6, 781-783
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Runikhina S. A., Chusov D. A. Hayashi ligand-based rhodium complex in carbon monoxide and molecular hydrogen-assisted reductive amination // Mendeleev Communications. 2021. Vol. 31. No. 6. pp. 781-783.
GOST all authors (up to 50) Copy
Runikhina S. A., Chusov D. A. Hayashi ligand-based rhodium complex in carbon monoxide and molecular hydrogen-assisted reductive amination // Mendeleev Communications. 2021. Vol. 31. No. 6. pp. 781-783.
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TY - JOUR
DO - 10.1016/j.mencom.2021.11.004
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.11.004
TI - Hayashi ligand-based rhodium complex in carbon monoxide and molecular hydrogen-assisted reductive amination
T2 - Mendeleev Communications
AU - Runikhina, Sofiya Alexandrovna
AU - Chusov, Denis Alexandrovich
PY - 2021
DA - 2021/11/08
PB - Mendeleev Communications
SP - 781-783
IS - 6
VL - 31
ER -
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@article{2021_Runikhina,
author = {Sofiya Alexandrovna Runikhina and Denis Alexandrovich Chusov},
title = {Hayashi ligand-based rhodium complex in carbon monoxide and molecular hydrogen-assisted reductive amination},
journal = {Mendeleev Communications},
year = {2021},
volume = {31},
publisher = {Mendeleev Communications},
month = {Nov},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.11.004},
number = {6},
pages = {781--783},
doi = {10.1016/j.mencom.2021.11.004}
}
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Runikhina, Sofiya Alexandrovna, and Denis Alexandrovich Chusov. “Hayashi ligand-based rhodium complex in carbon monoxide and molecular hydrogen-assisted reductive amination.” Mendeleev Communications, vol. 31, no. 6, Nov. 2021, pp. 781-783. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.11.004.

Keywords

aldehydes
amines
carbon monoxide
chiral complexes
diene complexes
Hayashi ligand
Ketones
reductive amination
rhodium complexes

Abstract

The CO- and H2-assisted reductive amination of carbonyl compounds catalyzed by stable chiral Hayashi ligand-based rhodium complex afforded the racemic amines in moderate yields. The racemic outcome of the process results from the elimination of the chiral ligand from the catalyst under the action of hydrogen or carbon monoxide as reductants.

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