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Gas-phase oxidative carbonylation of methane to acetic acid over zeolites

Konstantin Borisovich Golubev 1
Konstantin Borisovich Golubev
, 
Olga Vladimirovna Yashina 1
Olga Vladimirovna Yashina
, 
Natalia Nikolaevna Ezhova 1
Natalia Nikolaevna Ezhova
, 
Natalia N Kolesnichenko 1
Natalia N Kolesnichenko
10.1016/j.mencom.2021.09.040
Published 2021-09-08
Communication , Volume 31, Issue 5, 712-714
9
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Golubev K. B. et al. Gas-phase oxidative carbonylation of methane to acetic acid over zeolites // Mendeleev Communications. 2021. Vol. 31. No. 5. pp. 712-714.
GOST all authors (up to 50) Copy
Golubev K. B., Yashina O. V., Ezhova N. N., Kolesnichenko N. N. Gas-phase oxidative carbonylation of methane to acetic acid over zeolites // Mendeleev Communications. 2021. Vol. 31. No. 5. pp. 712-714.
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TY - JOUR
DO - 10.1016/j.mencom.2021.09.040
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.09.040
TI - Gas-phase oxidative carbonylation of methane to acetic acid over zeolites
T2 - Mendeleev Communications
AU - Golubev, Konstantin Borisovich
AU - Yashina, Olga Vladimirovna
AU - Ezhova, Natalia Nikolaevna
AU - Kolesnichenko, Natalia N
PY - 2021
DA - 2021/09/08
PB - Mendeleev Communications
SP - 712-714
IS - 5
VL - 31
ER -
BibTex
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@article{2021_Golubev,
author = {Konstantin Borisovich Golubev and Olga Vladimirovna Yashina and Natalia Nikolaevna Ezhova and Natalia N Kolesnichenko},
title = {Gas-phase oxidative carbonylation of methane to acetic acid over zeolites},
journal = {Mendeleev Communications},
year = {2021},
volume = {31},
publisher = {Mendeleev Communications},
month = {Sep},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.09.040},
number = {5},
pages = {712--714},
doi = {10.1016/j.mencom.2021.09.040}
}
MLA
Cite this
MLA Copy
Golubev, Konstantin Borisovich, et al. “Gas-phase oxidative carbonylation of methane to acetic acid over zeolites.” Mendeleev Communications, vol. 31, no. 5, Sep. 2021, pp. 712-714. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.09.040.

Keywords

acetic acid
acidity
oxidative carbonylation of methane
water vapor
ZSM-5 zeolites

Abstract

Gas-phase oxidative carbonylation of methane was first performed on ZSM-5 zeolites. The addition of water vapor to a mixture of carbonylation gases leads to a multiple (by two orders of magnitude) increase in acetic acid yield. Zeolites with high acidity, primarily Brønsted acidity, favor the target product formation.

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