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The first example of anodic corrosion of Pd in aqueous ethylenediamine with formation of colloidal palladium

Marina Dmitrievna Vedenyapina 1
Marina Dmitrievna Vedenyapina
, 
Vladimir Vladimirovich Kuznetsov 1
Vladimir Vladimirovich Kuznetsov
, 
Stanislav Andreevich Kulaishin 1
Stanislav Andreevich Kulaishin
, 
Nina Nikolaevna Makhova 1
Nina Nikolaevna Makhova
, 
Marina M Kazakova 1
Marina M Kazakova
10.1016/j.mencom.2021.09.015
Published 2021-09-08
Communication , Volume 31, Issue 5, 638-640
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Vedenyapina M. D. et al. The first example of anodic corrosion of Pd in aqueous ethylenediamine with formation of colloidal palladium // Mendeleev Communications. 2021. Vol. 31. No. 5. pp. 638-640.
GOST all authors (up to 50) Copy
Vedenyapina M. D., Kuznetsov V. V., Kulaishin S. A., Makhova N. N., Kazakova M. M. The first example of anodic corrosion of Pd in aqueous ethylenediamine with formation of colloidal palladium // Mendeleev Communications. 2021. Vol. 31. No. 5. pp. 638-640.
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TY - JOUR
DO - 10.1016/j.mencom.2021.09.015
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.09.015
TI - The first example of anodic corrosion of Pd in aqueous ethylenediamine with formation of colloidal palladium
T2 - Mendeleev Communications
AU - Vedenyapina, Marina Dmitrievna
AU - Kuznetsov, Vladimir Vladimirovich
AU - Kulaishin, Stanislav Andreevich
AU - Makhova, Nina Nikolaevna
AU - Kazakova, Marina M
PY - 2021
DA - 2021/09/08
PB - Mendeleev Communications
SP - 638-640
IS - 5
VL - 31
ER -
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@article{2021_Vedenyapina,
author = {Marina Dmitrievna Vedenyapina and Vladimir Vladimirovich Kuznetsov and Stanislav Andreevich Kulaishin and Nina Nikolaevna Makhova and Marina M Kazakova},
title = {The first example of anodic corrosion of Pd in aqueous ethylenediamine with formation of colloidal palladium},
journal = {Mendeleev Communications},
year = {2021},
volume = {31},
publisher = {Mendeleev Communications},
month = {Sep},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.09.015},
number = {5},
pages = {638--640},
doi = {10.1016/j.mencom.2021.09.015}
}
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MLA Copy
Vedenyapina, Marina Dmitrievna, et al. “The first example of anodic corrosion of Pd in aqueous ethylenediamine with formation of colloidal palladium.” Mendeleev Communications, vol. 31, no. 5, Sep. 2021, pp. 638-640. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.09.015.

Keywords

colloidal Pd
corrosion
electron microscopy
ethylenediamine
gravimetry
kinetics
palladium anode
voltammetry

Abstract

For the first time, corrosion of a Pd anode was detected during electrolysis in a weakly alkaline aqueous solution of ethylenediamine. The kinetics and mechanism of the process were investigated by the methods of cyclic voltammetry and gravimetry. Scanning electron microscopy showed corrosion of the Pd anode and deposition of Pd on the cathode surface, while the formation of colloidal Pd in the working solution was identified by transmission electron microscopy.

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