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Chemical design of heterometallic carboxylate structures with Fe3+ and Ag+ ions as a rational synthetic approach

, 
Mikhail Aleksandrovich Kiskin 1
Mikhail Aleksandrovich Kiskin
, 
Dmitry Evgenievich Baravikov 1
Dmitry Evgenievich Baravikov
,  ,  , 
10.1016/j.mencom.2021.09.012
Published 2021-09-08
Communication , Volume 31, Issue 5, 628-630
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Lutsenko I. A. et al. Chemical design of heterometallic carboxylate structures with Fe3+ and Ag+ ions as a rational synthetic approach // Mendeleev Communications. 2021. Vol. 31. No. 5. pp. 628-630.
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Lutsenko I. A., Kiskin M. A., Baravikov D. E., Nelyubina Y. V., Primakov P. V., Eremenko I. L. Chemical design of heterometallic carboxylate structures with Fe3+ and Ag+ ions as a rational synthetic approach // Mendeleev Communications. 2021. Vol. 31. No. 5. pp. 628-630.
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TY - JOUR
DO - 10.1016/j.mencom.2021.09.012
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.09.012
TI - Chemical design of heterometallic carboxylate structures with Fe3+ and Ag+ ions as a rational synthetic approach
T2 - Mendeleev Communications
AU - Lutsenko, Irina Aleksandrovna
AU - Kiskin, Mikhail Aleksandrovich
AU - Baravikov, Dmitry Evgenievich
AU - Nelyubina, Yulia Vladimirovna
AU - Primakov, Petr Vital'evich
AU - Eremenko, Igor Leonidovich
PY - 2021
DA - 2021/09/08
PB - Mendeleev Communications
SP - 628-630
IS - 5
VL - 31
ER -
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@article{2021_Lutsenko,
author = {Irina Aleksandrovna Lutsenko and Mikhail Aleksandrovich Kiskin and Dmitry Evgenievich Baravikov and Yulia Vladimirovna Nelyubina and Petr Vital'evich Primakov and Igor Leonidovich Eremenko},
title = {Chemical design of heterometallic carboxylate structures with Fe3+ and Ag+ ions as a rational synthetic approach},
journal = {Mendeleev Communications},
year = {2021},
volume = {31},
publisher = {Mendeleev Communications},
month = {Sep},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.09.012},
number = {5},
pages = {628--630},
doi = {10.1016/j.mencom.2021.09.012}
}
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Lutsenko, Irina Aleksandrovna, et al. “Chemical design of heterometallic carboxylate structures with Fe3+ and Ag+ ions as a rational synthetic approach.” Mendeleev Communications, vol. 31, no. 5, Sep. 2021, pp. 628-630. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.09.012.

Keywords

crystal structure
heteroleptic complex
iron complex
silver
solid phase thermolysis

Abstract

Solid phase thermolysis of pivalate complex [Fe3O(Piv)6(HPiv)3]Piv generates the [Fe3O(Piv)6]+ complex cation due to a deficiency of ligands in the coordination sphere of the metal ions. Crystallization of [Fe3O(Piv)6]+ from THF–EtOH leads to the heteroleptic complex [Fe3O(Piv)6(THF)(EtOH)(OH)] · 0.5 THF · 0.5 H2O in 69% yield, while the reaction of [Fe3O(Piv)6]+ with AgNO3 in toluene results in the complex [Fe4Ag4O2(Piv)12] · 2 PhMe with a rare combination of FeIII and AgI atoms. Crystal structures of the two new complexes have been established.

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