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A new P-heterocyclic type of phosphonium–iodonium ylides based on dibenzophosphole

Anton Sergeevich Nenashev 1
Anton Sergeevich Nenashev
, 
Dmitry Alekseevich Dospekhov 1
Dmitry Alekseevich Dospekhov
, 
Tatyana Aleksandrovna Podrugina 1
Tatyana Aleksandrovna Podrugina
10.1016/j.mencom.2021.09.009
Published 2021-09-08
Communication , Volume 31, Issue 5, 618-619
8
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Nenashev A. S., Dospekhov D. A., Podrugina T. A. A new P-heterocyclic type of phosphonium–iodonium ylides based on dibenzophosphole // Mendeleev Communications. 2021. Vol. 31. No. 5. pp. 618-619.
GOST all authors (up to 50) Copy
Nenashev A. S., Dospekhov D. A., Podrugina T. A. A new P-heterocyclic type of phosphonium–iodonium ylides based on dibenzophosphole // Mendeleev Communications. 2021. Vol. 31. No. 5. pp. 618-619.
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TY - JOUR
DO - 10.1016/j.mencom.2021.09.009
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.09.009
TI - A new P-heterocyclic type of phosphonium–iodonium ylides based on dibenzophosphole
T2 - Mendeleev Communications
AU - Nenashev, Anton Sergeevich
AU - Dospekhov, Dmitry Alekseevich
AU - Podrugina, Tatyana Aleksandrovna
PY - 2021
DA - 2021/09/08
PB - Mendeleev Communications
SP - 618-619
IS - 5
VL - 31
ER -
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@article{2021_Nenashev,
author = {Anton Sergeevich Nenashev and Dmitry Alekseevich Dospekhov and Tatyana Aleksandrovna Podrugina},
title = {A new P-heterocyclic type of phosphonium–iodonium ylides based on dibenzophosphole},
journal = {Mendeleev Communications},
year = {2021},
volume = {31},
publisher = {Mendeleev Communications},
month = {Sep},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.09.009},
number = {5},
pages = {618--619},
doi = {10.1016/j.mencom.2021.09.009}
}
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Nenashev, Anton Sergeevich, et al. “A new P-heterocyclic type of phosphonium–iodonium ylides based on dibenzophosphole.” Mendeleev Communications, vol. 31, no. 5, Sep. 2021, pp. 618-619. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.09.009.

Abstract

A novel mixed phosphonium–iodonium ylide was synthesized by alkylation of 5-phenyl-5H-dibenzophosphole with phenacyl bromide followed by deprotonation and oxidation of the resulting phosphonium ylide with (diacetoxyiodo)- benzene. The influence of the cyclic nature of the phosphonium moiety on the dynamic E/Z isomerism in the mixed ylide is discussed.

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