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Conformational energy (A-value) of the 4-phenyl-1,2,3-triazolyl group

Mulinde R Ruyonga 1
Mulinde R Ruyonga
, 
Vyacheslav Vladimirovich Samoshin 1
Vyacheslav Vladimirovich Samoshin
10.1016/j.mencom.2021.09.006
Published 2021-09-08
Communication , Volume 31, Issue 5, 609-611
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Ruyonga M. R., Samoshin V. V. Conformational energy (A-value) of the 4-phenyl-1,2,3-triazolyl group // Mendeleev Communications. 2021. Vol. 31. No. 5. pp. 609-611.
GOST all authors (up to 50) Copy
Ruyonga M. R., Samoshin V. V. Conformational energy (A-value) of the 4-phenyl-1,2,3-triazolyl group // Mendeleev Communications. 2021. Vol. 31. No. 5. pp. 609-611.
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TY - JOUR
DO - 10.1016/j.mencom.2021.09.006
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.09.006
TI - Conformational energy (A-value) of the 4-phenyl-1,2,3-triazolyl group
T2 - Mendeleev Communications
AU - Ruyonga, Mulinde R
AU - Samoshin, Vyacheslav Vladimirovich
PY - 2021
DA - 2021/09/08
PB - Mendeleev Communications
SP - 609-611
IS - 5
VL - 31
ER -
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@article{2021_Ruyonga,
author = {Mulinde R Ruyonga and Vyacheslav Vladimirovich Samoshin},
title = {Conformational energy (A-value) of the 4-phenyl-1,2,3-triazolyl group},
journal = {Mendeleev Communications},
year = {2021},
volume = {31},
publisher = {Mendeleev Communications},
month = {Sep},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.09.006},
number = {5},
pages = {609--611},
doi = {10.1016/j.mencom.2021.09.006}
}
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Ruyonga, Mulinde R., and Vyacheslav Vladimirovich Samoshin. “Conformational energy (A-value) of the 4-phenyl-1,2,3-triazolyl group.” Mendeleev Communications, vol. 31, no. 5, Sep. 2021, pp. 609-611. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.09.006.

Keywords

(1,2,3-triazol-1-yl)cyclohexane conformations
click reaction
cyclohexyl-1,2,3-triazol
triazolyl conformational energy

Abstract

Conformational energy (A-value) of the 4-phenyl-1,2,3- triazolyl group was estimated as 2.0 kcal mol–1 (8.5 kJ mol–1) using 1H NMR-based conformational study for a set of (4-phenyl-1,2,3-triazol-1-yl)cyclohexanes. This provides a reasonable estimation also for the conformational energy of 1,2,3-triazolyl group itself and its substituted analogues.

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