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Transformations of (ferrocenylmethylidene)malononitrile under the action of molecular sulfur and NaHS

Jessica J Sánchez García 1
Jessica J Sánchez García
, 
Gustavo Huerta Vargas 1
Gustavo Huerta Vargas
, 
Marcos Flores-Alamo 1
Marcos Flores-Alamo
, 
Elena Ivanovna Klimova 1
Elena Ivanovna Klimova
10.1016/j.mencom.2021.07.038
Published 2021-07-07
Communication , Volume 31, Issue 4, 550-551
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Sánchez García J. J. et al. Transformations of (ferrocenylmethylidene)malononitrile under the action of molecular sulfur and NaHS // Mendeleev Communications. 2021. Vol. 31. No. 4. pp. 550-551.
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Sánchez García J. J., Huerta Vargas G., Flores-Alamo M., Klimova E. I. Transformations of (ferrocenylmethylidene)malononitrile under the action of molecular sulfur and NaHS // Mendeleev Communications. 2021. Vol. 31. No. 4. pp. 550-551.
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TY - JOUR
DO - 10.1016/j.mencom.2021.07.038
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.07.038
TI - Transformations of (ferrocenylmethylidene)malononitrile under the action of molecular sulfur and NaHS
T2 - Mendeleev Communications
AU - Sánchez García, Jessica J
AU - Huerta Vargas, Gustavo
AU - Flores-Alamo, Marcos
AU - Klimova, Elena Ivanovna
PY - 2021
DA - 2021/07/07
PB - Mendeleev Communications
SP - 550-551
IS - 4
VL - 31
ER -
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@article{2021_Sánchez García,
author = {Jessica J Sánchez García and Gustavo Huerta Vargas and Marcos Flores-Alamo and Elena Ivanovna Klimova},
title = {Transformations of (ferrocenylmethylidene)malononitrile under the action of molecular sulfur and NaHS},
journal = {Mendeleev Communications},
year = {2021},
volume = {31},
publisher = {Mendeleev Communications},
month = {Jul},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.07.038},
number = {4},
pages = {550--551},
doi = {10.1016/j.mencom.2021.07.038}
}
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Sánchez García, Jessica J., et al. “Transformations of (ferrocenylmethylidene)malononitrile under the action of molecular sulfur and NaHS.” Mendeleev Communications, vol. 31, no. 4, Jul. 2021, pp. 550-551. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.07.038.

Abstract

Reaction of (ferrocenylmethylidene)malononitrile with molecular sulfur and NaHS in PriOH/H2O medium gives (di)ferrocenyl-substituted 3-imino-, 3-oxo- and 3-thioxo-1,2-dithioles, ferrocenyl-substituted aminoisophthalonitrile and pyridine derivatives as well as products of fragmentation of the starting reactant. The posible mechanism for their formation is discussed.

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