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Three dimensional aromaticity in pyramidanes C4R4E and Ge4R4Ge

Rinat Ravil'evich Aysin 1
Rinat Ravil'evich Aysin
, 
Sergei Sergeevich Bukalov 1
Sergei Sergeevich Bukalov
10.1016/j.mencom.2021.07.014
Published 2021-07-07
Communication , Volume 31, Issue 4, 481-483
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Aysin R. R., Bukalov S. S. Three dimensional aromaticity in pyramidanes C4R4E and Ge4R4Ge // Mendeleev Communications. 2021. Vol. 31. No. 4. pp. 481-483.
GOST all authors (up to 50) Copy
Aysin R. R., Bukalov S. S. Three dimensional aromaticity in pyramidanes C4R4E and Ge4R4Ge // Mendeleev Communications. 2021. Vol. 31. No. 4. pp. 481-483.
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TY - JOUR
DO - 10.1016/j.mencom.2021.07.014
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.07.014
TI - Three dimensional aromaticity in pyramidanes C4R4E and Ge4R4Ge
T2 - Mendeleev Communications
AU - Aysin, Rinat Ravil'evich
AU - Bukalov, Sergei Sergeevich
PY - 2021
DA - 2021/07/07
PB - Mendeleev Communications
SP - 481-483
IS - 4
VL - 31
ER -
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@article{2021_Aysin,
author = {Rinat Ravil'evich Aysin and Sergei Sergeevich Bukalov},
title = {Three dimensional aromaticity in pyramidanes C4R4E and Ge4R4Ge},
journal = {Mendeleev Communications},
year = {2021},
volume = {31},
publisher = {Mendeleev Communications},
month = {Jul},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.07.014},
number = {4},
pages = {481--483},
doi = {10.1016/j.mencom.2021.07.014}
}
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Aysin, Rinat Ravil'evich, and Sergei Sergeevich Bukalov. “Three dimensional aromaticity in pyramidanes C4R4E and Ge4R4Ge.” Mendeleev Communications, vol. 31, no. 4, Jul. 2021, pp. 481-483. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.07.014.

Abstract

Three dimensional aromaticity in pyramidanes C4(SiMe3)4E (E = Ge, Sn, Pb, P+, BCl, Mg) and Ge4(SiMe3)4Ge was investigated using gauge-included magnetically induced currents and electron density of delocalized bonds as two criteria. For the C4(SiMe3)4E compounds, different series of the aromaticity degree have been obtained by the two methods, respectively: P > Ge ≥ Sn ∼ Pb > B and Pb ≥ Sn ≥ Ge > B > P. Two isomers of Ge4(SiMe3)4Ge possess nearly equal aromaticity.

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