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A lead(II) toluene complex

Julian Messelberger 1
Julian Messelberger
, 
Piermaria Pinter 1, 2
Piermaria Pinter
, 
Frank W Heinemann 2
Frank W Heinemann
, 
Dominik Munz 1
Dominik Munz
10.1016/j.mencom.2021.07.011
Published 2021-07-07
Communication , Volume 31, Issue 4, 471-474
3
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Messelberger J. et al. A lead(II) toluene complex // Mendeleev Communications. 2021. Vol. 31. No. 4. pp. 471-474.
GOST all authors (up to 50) Copy
Messelberger J., Pinter P., Heinemann F. W., Munz D. A lead(II) toluene complex // Mendeleev Communications. 2021. Vol. 31. No. 4. pp. 471-474.
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TY - JOUR
DO - 10.1016/j.mencom.2021.07.011
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.07.011
TI - A lead(II) toluene complex
T2 - Mendeleev Communications
AU - Messelberger, Julian
AU - Pinter, Piermaria
AU - Heinemann, Frank W
AU - Munz, Dominik
PY - 2021
DA - 2021/07/07
PB - Mendeleev Communications
SP - 471-474
IS - 4
VL - 31
ER -
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@article{2021_Messelberger,
author = {Julian Messelberger and Piermaria Pinter and Frank W Heinemann and Dominik Munz},
title = {A lead(II) toluene complex},
journal = {Mendeleev Communications},
year = {2021},
volume = {31},
publisher = {Mendeleev Communications},
month = {Jul},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.07.011},
number = {4},
pages = {471--474},
doi = {10.1016/j.mencom.2021.07.011}
}
MLA
Cite this
MLA Copy
Messelberger, Julian, et al. “A lead(II) toluene complex.” Mendeleev Communications, vol. 31, no. 4, Jul. 2021, pp. 471-474. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.07.011.

Abstract

A well-defined intermolecular toluene complex of lead(II) supported by a pincer-type saNHC (saturated N-heterocyclic carbene) ligand was prepared through deprotonation of the bis(imidazolinium) salt with Pb[N(SiMe3)2]2 or metalation of the free carbene and subsequent salt metathesis with Tl(OTf), followed by crystallization from toluene. Combined computational and experimental results indicate that noncovalent interactions with the lead atom (σ-sss-hole type interaction, dispersion) and the diisopropylphenyl side groups of the ligand (dispersion) stabilize the complex.

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