Home / Publications / Effect of the heat treatment of CH3NH3PbI3 perovskite on its electrical and photoelectric properties

Effect of the heat treatment of CH3NH3PbI3 perovskite on its electrical and photoelectric properties

Dmitriy Valerievich Amasev 1
Dmitriy Valerievich Amasev
, 
Shamil Rashitovich Saitov 2
Shamil Rashitovich Saitov
, 
Vladislav Georgievich Mikhalevich 1
Vladislav Georgievich Mikhalevich
, 
Alexey Raisovich Tameev 3
Alexey Raisovich Tameev
, 
Andrey Georgievich Kazanskii 2
Andrey Georgievich Kazanskii
10.1016/j.mencom.2021.07.010
Published 2021-07-07
Communication , Volume 31, Issue 4, 469-470
4
Share
Cite this
GOST
 | 
Cite this
GOST Copy
Amasev D. V. et al. Effect of the heat treatment of CH3NH3PbI3 perovskite on its electrical and photoelectric properties // Mendeleev Communications. 2021. Vol. 31. No. 4. pp. 469-470.
GOST all authors (up to 50) Copy
Amasev D. V., Saitov S. R., Mikhalevich V. G., Tameev A. R., Kazanskii A. G. Effect of the heat treatment of CH3NH3PbI3 perovskite on its electrical and photoelectric properties // Mendeleev Communications. 2021. Vol. 31. No. 4. pp. 469-470.
RIS
 | 
Cite this
RIS Copy
TY - JOUR
DO - 10.1016/j.mencom.2021.07.010
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.07.010
TI - Effect of the heat treatment of CH3NH3PbI3 perovskite on its electrical and photoelectric properties
T2 - Mendeleev Communications
AU - Amasev, Dmitriy Valerievich
AU - Saitov, Shamil Rashitovich
AU - Mikhalevich, Vladislav Georgievich
AU - Tameev, Alexey Raisovich
AU - Kazanskii, Andrey Georgievich
PY - 2021
DA - 2021/07/07
PB - Mendeleev Communications
SP - 469-470
IS - 4
VL - 31
ER -
BibTex
 | 
Cite this
BibTex (up to 50 authors) Copy
@article{2021_Amasev,
author = {Dmitriy Valerievich Amasev and Shamil Rashitovich Saitov and Vladislav Georgievich Mikhalevich and Alexey Raisovich Tameev and Andrey Georgievich Kazanskii},
title = {Effect of the heat treatment of CH3NH3PbI3 perovskite on its electrical and photoelectric properties},
journal = {Mendeleev Communications},
year = {2021},
volume = {31},
publisher = {Mendeleev Communications},
month = {Jul},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.07.010},
number = {4},
pages = {469--470},
doi = {10.1016/j.mencom.2021.07.010}
}
MLA
Cite this
MLA Copy
Amasev, Dmitriy Valerievich, et al. “Effect of the heat treatment of CH3NH3PbI3 perovskite on its electrical and photoelectric properties.” Mendeleev Communications, vol. 31, no. 4, Jul. 2021, pp. 469-470. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.07.010.

Keywords

activation energy
decomposition
degradation
perovskites
photoconductivity
spectra
temperature annealing

Abstract

The effect of the annealing of CH3NH3PbI3 perovskite on its electrical, photoelectric and optical properties has been estimated. The annealing leads to a two-phase structure consisting of perovskite and lead iodide, whose relative concentrations depend on the annealing temperature. The formation of a PbI2 phase in a perovskite film upon heating leads to a decrease in the conductivity and photoconductivity of two-phase material, which contradicts the assumption of a decrease in recombination associated with PbI2, obtained by measuring the parameters of a solar cell.

References

1.
Solar cell efficiency tables (Version 55)
Green M.A., Dunlop E.D., Hohl‐Ebinger J., Yoshita M., Kopidakis N., Ho‐Baillie A.W.
Progress in Photovoltaics: Research and Applications, 2019
2.
Physicochemical approaches for optimization of perovskite solar cell performance
Nikolskaia A.B., Vildanova M.F., Kozlov S.S., Shevaleevskiy O.I.
Russian Chemical Bulletin, 2020
3.
Thin-film semiconductor perspective of organometal trihalide perovskite materials for high-efficiency solar cells
Xiao Z., Yuan Y., Wang Q., Shao Y., Bai Y., Deng Y., Dong Q., Hu M., Bi C., Huang J.
Materials Science and Engineering: R: Reports, 2016
4.
10.1016/j.mencom.2021.07.010_b0020
Cao
APL Mater., 2014
5.
Investigation of Thermally Induced Degradation in CH3NH3PbI3 Perovskite Solar Cells using In-situ Synchrotron Radiation Analysis
Kim N., Min Y.H., Noh S., Cho E., Jeong G., Joo M., Ahn S., Lee J.S., Kim S., Ihm K., Ahn H., Kang Y., Lee H., Kim D.
Scientific Reports, 2017
6.
Layer-by-Layer Degradation of Methylammonium Lead Tri-iodide Perovskite Microplates
Fan Z., Xiao H., Wang Y., Zhao Z., Lin Z., Cheng H., Lee S., Wang G., Feng Z., Goddard W.A., Huang Y., Duan X.
Joule, 2017
7.
Beneficial Effects of PbI2 Incorporated in Organo‐Lead Halide Perovskite Solar Cells
Kim Y.C., Jeon N.J., Noh J.H., Yang W.S., Seo J., Yun J.S., Ho-Baillie A., Huang S., Green M.A., Seidel J., Ahn T.K., Seok S.I.
Advanced Energy Materials, 2015
8.
Formation, location and beneficial role of PbI2 in lead halide perovskite solar cells
Du T., Burgess C.H., Kim J., Zhang J., Durrant J.R., McLachlan M.A.
Sustainable Energy and Fuels, 2017
9.
10.1016/j.mencom.2021.07.010_b0045
Mott
Electronic Processes in Non-Crystalline Materials, 1979