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New indoline spiropyrans with highly stable merocyanine forms

Anastasia Sergeevna Kozlenko 1
Anastasia Sergeevna Kozlenko
, 
Nadezhda Ivanovna Makarova 1
Nadezhda Ivanovna Makarova
, 
Ilya Vyacheslavovich Ozhogin 1
Ilya Vyacheslavovich Ozhogin
, 
Artem Dmitrievich Pugachev 1
Artem Dmitrievich Pugachev
, 
Maria Borisovna Lukyanova 1
Maria Borisovna Lukyanova
, 
Irina Aleksandrovna Rostovtseva 1
Irina Aleksandrovna Rostovtseva
, 
Gennadii Sergeevich Borodkin 1
Gennadii Sergeevich Borodkin
, 
Natalia Victorovna Stankevich 1
Natalia Victorovna Stankevich
, 
Anatolii Viktorovich Metelitsa 1
Anatolii Viktorovich Metelitsa
, 
Boris S Lukyanov 1
Boris S Lukyanov
10.1016/j.mencom.2021.04.040
Published 2021-04-28
Communication , Volume 31, Issue 3, 403-406
19
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Kozlenko A. S. et al. New indoline spiropyrans with highly stable merocyanine forms // Mendeleev Communications. 2021. Vol. 31. No. 3. pp. 403-406.
GOST all authors (up to 50) Copy
Kozlenko A. S., Makarova N. I., Ozhogin I. V., Pugachev A. D., Lukyanova M. B., Rostovtseva I. A., Borodkin G. S., Stankevich N. V., Metelitsa A. V., Lukyanov B. S. New indoline spiropyrans with highly stable merocyanine forms // Mendeleev Communications. 2021. Vol. 31. No. 3. pp. 403-406.
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TY - JOUR
DO - 10.1016/j.mencom.2021.04.040
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.04.040
TI - New indoline spiropyrans with highly stable merocyanine forms
T2 - Mendeleev Communications
AU - Kozlenko, Anastasia Sergeevna
AU - Makarova, Nadezhda Ivanovna
AU - Ozhogin, Ilya Vyacheslavovich
AU - Pugachev, Artem Dmitrievich
AU - Lukyanova, Maria Borisovna
AU - Rostovtseva, Irina Aleksandrovna
AU - Borodkin, Gennadii Sergeevich
AU - Stankevich, Natalia Victorovna
AU - Metelitsa, Anatolii Viktorovich
AU - Lukyanov, Boris S
PY - 2021
DA - 2021/04/28
PB - Mendeleev Communications
SP - 403-406
IS - 3
VL - 31
ER -
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@article{2021_Kozlenko,
author = {Anastasia Sergeevna Kozlenko and Nadezhda Ivanovna Makarova and Ilya Vyacheslavovich Ozhogin and Artem Dmitrievich Pugachev and Maria Borisovna Lukyanova and Irina Aleksandrovna Rostovtseva and Gennadii Sergeevich Borodkin and Natalia Victorovna Stankevich and Anatolii Viktorovich Metelitsa and Boris S Lukyanov},
title = {New indoline spiropyrans with highly stable merocyanine forms},
journal = {Mendeleev Communications},
year = {2021},
volume = {31},
publisher = {Mendeleev Communications},
month = {Apr},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.04.040},
number = {3},
pages = {403--406},
doi = {10.1016/j.mencom.2021.04.040}
}
MLA
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MLA Copy
Kozlenko, Anastasia Sergeevna, et al. “New indoline spiropyrans with highly stable merocyanine forms.” Mendeleev Communications, vol. 31, no. 3, Apr. 2021, pp. 403-406. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.04.040.

Keywords

bathochromic shift
cationic fragment
indolinium salts
merocyanine
molecular switch
photochromism
spiropyrans

Abstract

New spiropyrans with chromene and indoline cores bearing alkoxycarbonyl group and cationic π-acceptor in the chromene moiety were synthesized in one step from 1,2,3,3-tetramethylindolinium and isophthalic dialdehyde derivatives. The appending of a 8′-positioned conjugated cationic fragment causes a significant red-shift of the photoinduced isomers absorption maxima and provides them with extremely long lifetimes up to 75min. The obtained spiropyrans exhibit both positive and negative photochromism in solutions, demonstrating the properties of ‘photochromic balance’.

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