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Buchwald ligand-assisted Suzuki cross-coupling of polychlorobenzenes

Andrei Alexandrovich Vasil'ev 1
Andrei Alexandrovich Vasil'ev
, 
Alexander Sergeyevich Burukin 1
Alexander Sergeyevich Burukin
, 
Galina Mikhailovna Zhdankina 1
Galina Mikhailovna Zhdankina
, 
Sergei Grigorievich Zlotin 1
Sergei Grigorievich Zlotin
10.1016/j.mencom.2021.04.039
Published 2021-04-28
Communication , Volume 31, Issue 3, 400-402
7
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Vasil'ev A. A. et al. Buchwald ligand-assisted Suzuki cross-coupling of polychlorobenzenes // Mendeleev Communications. 2021. Vol. 31. No. 3. pp. 400-402.
GOST all authors (up to 50) Copy
Vasil'ev A. A., Burukin A. S., Zhdankina G. M., Zlotin S. G. Buchwald ligand-assisted Suzuki cross-coupling of polychlorobenzenes // Mendeleev Communications. 2021. Vol. 31. No. 3. pp. 400-402.
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TY - JOUR
DO - 10.1016/j.mencom.2021.04.039
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.04.039
TI - Buchwald ligand-assisted Suzuki cross-coupling of polychlorobenzenes
T2 - Mendeleev Communications
AU - Vasil'ev, Andrei Alexandrovich
AU - Burukin, Alexander Sergeyevich
AU - Zhdankina, Galina Mikhailovna
AU - Zlotin, Sergei Grigorievich
PY - 2021
DA - 2021/04/28
PB - Mendeleev Communications
SP - 400-402
IS - 3
VL - 31
ER -
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@article{2021_Vasil'ev,
author = {Andrei Alexandrovich Vasil'ev and Alexander Sergeyevich Burukin and Galina Mikhailovna Zhdankina and Sergei Grigorievich Zlotin},
title = {Buchwald ligand-assisted Suzuki cross-coupling of polychlorobenzenes},
journal = {Mendeleev Communications},
year = {2021},
volume = {31},
publisher = {Mendeleev Communications},
month = {Apr},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.04.039},
number = {3},
pages = {400--402},
doi = {10.1016/j.mencom.2021.04.039}
}
MLA
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Vasil'ev, Andrei Alexandrovich, et al. “Buchwald ligand-assisted Suzuki cross-coupling of polychlorobenzenes.” Mendeleev Communications, vol. 31, no. 3, Apr. 2021, pp. 400-402. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.04.039.

Keywords

arylboronic acids
biaryls
Buchwald ligands
cross-coupling
polychloroarenes

Abstract

Screening of four Buchwald ligands for the cross-coupling of isomeric di-, tri- and tetrachlorobenzenes with arylboronic acids revealed that good yields of exhaustive substitution can be best provided by 2-dicyclohexylphosphino-2′-(dimethylamino) biphenyl (DavePHOS).

References

1.
Catalytic hydrodechlorination of chlorophenols
Hoke J.B., Gramiccioni G.A., Balko E.N.
Applied Catalysis B: Environmental, 1992
5.
10.1016/j.mencom.2021.04.039_sbref0010a
Polychloroaromatic Compounds, 1974
6.
Chemical methods of transformation of polychlorobiphenyls
Gorbunova T.I., Saloutin V.I., Chupakhin O.N.
Russian Chemical Reviews, 2010
7.
Chemical functionalisation of polychloroarenes
Vasil'ev A.A., Burukin A.S., Zlotin S.G.
Russian Chemical Reviews, 2007
9.
Cross-coupling of polychlorobenzenes with phenylboronic acid in the presence of [Pd]-imidazolium salts as catalytic systems
Burukin A.S., Vasil’ev A.A., Merkulova N.L., Chizhov A.O., Mistryukov E.A., Zlotin S.G.
Russian Chemical Bulletin, 2007
10.
Bis(tetrazolyl)benzenes as ligands in the Suzuki reaction: Promoters or inhibitors?
Burukin A.S., Vasil’ev A.A., Merkulova N.L., Struchkova M.I., Zlotin S.G.
Russian Chemical Bulletin, 2006
11.
A. S. Burukin, PhD Thesis, 2006.
12.
Highly Active Palladium Catalysts for Suzuki Coupling Reactions
Wolfe J.P., Singer R.A., Yang B.H., Buchwald S.L.
Journal of the American Chemical Society, 1999
13.
Simple, Efficient Catalyst System for the Palladium-Catalyzed Amination of Aryl Chlorides, Bromides, and Triflates
Wolfe J.P., Tomori H., Sadighi J.P., Yin J., Buchwald S.L.
Journal of Organic Chemistry, 2000
14.
An Extremely Active Catalyst for the Negishi Cross-Coupling Reaction
Milne J.E., Buchwald S.L.
Journal of the American Chemical Society, 2004
15.
Catalysts for Suzuki−Miyaura Coupling Processes:  Scope and Studies of the Effect of Ligand Structure
Barder T.E., Walker S.D., Martinelli J.R., Buchwald S.L.
Journal of the American Chemical Society, 2005
21.
Gribanov P.S., Chesnokov G.A., Dzhevakov P.B., Kirilenko N.Y., Rzhevskiy S.A., Ageshina A.A., Topchiy M.A., Bermeshev M.V., Asachenko A.F., Nechaev M.S.
Mendeleev Communications, 2019
22.
Nickel(ii) N-heterocyclic carbene complexes as efficient catalysts for the Suzuki—Miyaura reaction
Soliev S.B., Astakhov A.V., Pasyukov D.V., Chernyshev V.M.
Russian Chemical Bulletin, 2020
23.
Verbitskiy E.V., Dinastiya E.M., Eltsov O.S., Zhilina E.F., Schepochkin A.V., Rusinov G.L., Chupakhin O.N., Charushin V.N.
Mendeleev Communications, 2020
24.
Matyugina E.S., Khandazhinskaya A.L., Kochetkov S.N., Seley-Radtke K.L.
Mendeleev Communications, 2020