Keywords
1,3,5-tris[4-(3,5-diphenylphenyl)phenyl]benzene
4-acetyl-3′,5′-diphenyl(biphenyl)
phenylene dendrimers
thermal stability
Abstract
A second generation phenylene dendrimer, viz. 1,3,5-tris[4-(3,5-diphenylphenyl)phenyl]benzene, was synthesized by cyclocondensation of 4-acetyl-3′,5′-diphenyl(biphenyl). This compound on heating to 600°C is transformed into substance possessing extremely heat-stable secondary structure. It retains the aromatic structure at this temperature and when heated to 1000°C is converted into material with graphite-like structure.
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