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Synthesis and crystal structure of the pyridinium acid nitrate [(PyH)2(NO3)][H2(NO3)3] containing a dihydrogen trinitrate anion

, 
Andrew Igorevich Shilov 1
Andrew Igorevich Shilov
, 
Alexander Ivanovich Boltalin 1
Alexander Ivanovich Boltalin
,  , 
Igor Viktorovich Morozov 1
Igor Viktorovich Morozov
10.1016/j.mencom.2021.04.024
Published 2021-04-28
Communication , Volume 31, Issue 3, 356-358
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Vorobyova A. A. et al. Synthesis and crystal structure of the pyridinium acid nitrate [(PyH)2(NO3)][H2(NO3)3] containing a dihydrogen trinitrate anion // Mendeleev Communications. 2021. Vol. 31. No. 3. pp. 356-358.
GOST all authors (up to 50) Copy
Vorobyova A. A., Shilov A. I., Boltalin A. I., Troyanov S. I., Morozov I. V. Synthesis and crystal structure of the pyridinium acid nitrate [(PyH)2(NO3)][H2(NO3)3] containing a dihydrogen trinitrate anion // Mendeleev Communications. 2021. Vol. 31. No. 3. pp. 356-358.
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TY - JOUR
DO - 10.1016/j.mencom.2021.04.024
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.04.024
TI - Synthesis and crystal structure of the pyridinium acid nitrate [(PyH)2(NO3)][H2(NO3)3] containing a dihydrogen trinitrate anion
T2 - Mendeleev Communications
AU - Vorobyova, Anna Andreevna
AU - Shilov, Andrew Igorevich
AU - Boltalin, Alexander Ivanovich
AU - Troyanov, Sergey Igorevich
AU - Morozov, Igor Viktorovich
PY - 2021
DA - 2021/04/28
PB - Mendeleev Communications
SP - 356-358
IS - 3
VL - 31
ER -
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@article{2021_Vorobyova,
author = {Anna Andreevna Vorobyova and Andrew Igorevich Shilov and Alexander Ivanovich Boltalin and Sergey Igorevich Troyanov and Igor Viktorovich Morozov},
title = {Synthesis and crystal structure of the pyridinium acid nitrate [(PyH)2(NO3)][H2(NO3)3] containing a dihydrogen trinitrate anion},
journal = {Mendeleev Communications},
year = {2021},
volume = {31},
publisher = {Mendeleev Communications},
month = {Apr},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.04.024},
number = {3},
pages = {356--358},
doi = {10.1016/j.mencom.2021.04.024}
}
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Vorobyova, Anna Andreevna, et al. “Synthesis and crystal structure of the pyridinium acid nitrate [(PyH)2(NO3)][H2(NO3)3] containing a dihydrogen trinitrate anion.” Mendeleev Communications, vol. 31, no. 3, Apr. 2021, pp. 356-358. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.04.024.

Keywords

acid salts
crystal structure
dihydrogen trinitrate
hydrogen bond
Ionic liquid

Abstract

A new protic room-temperature ionic liquid (Tc=14 ± 1°C) – pyridinium hydrogen dinitrate – was obtained from a solution of pyridinium nitrate in anhydrous nitric acid in a desiccator with P2O5. According to single crystal X-ray diffraction data, the solid state structure of [(PyH)2(NO3)][H2(NO3)3] consists of hydrogen bonded cations [(PyH)2(NO3)]+ and anions [(NO3)(HNO3)2]− with a previously unknown configuration containing two HNO3 molecules linked via hydrogen bonds to the central NO3- anion by the sin–anti type.

References

1.
MNDO study of some condensed (HnFn+1)− anions
Glidewell C.
Journal of Molecular Structure THEOCHEM, 1981
2.
Morozov I.V., Kemnitz E., Troyanov S.I.
Mendeleev Communications, 2020
3.
The crystal structure of ammonium trinitrate, NH4NO3.2HNO3
Duke J.R., Llewellyn F.J.
Acta Crystallographica, 1950
6.
The structure of the hydrogen dinitrate ion in tetraphenylarsonium hydrogen dinitrate
Faithful B.D., Wallwork S.C.
Chemical Communications (London), 1967
7.
Structure cristalline du dinitrate d'o-phénanthroline, C12H8N2.2HNO3
Thevenet G., Rodier N.
Acta Crystallographica Section B, 1978
8.
Adducts of coordination compounds—12
Al-Zamil N.S., Evans E.H., Gillard R.D., James D.W., Jenkins T.E., Lancashire R.J., Williams P.A.
Polyhedron, 1982
9.
10.1016/j.mencom.2021.04.024_bib0045
Huta
Acta Crystallogr., 2002
11.
The Structural Systematics of Protonation of Some Important Nitrogen-base Ligands. I Some Univalent Anion Salts of Doubly Protonated 2, 2′:6′, 2″-Terpyridyl
Junk P.C., Kepert C.J., Semenova L.I., Skelton B.W., White A.H.
Zeitschrift fur Anorganische und Allgemeine Chemie, 2006
12.
A refinement of the crystal structure of NH4NO3.2HNO3
Einstein F.W., Tuck D.G.
Acta Crystallographica Section B, 1970
13.
10.1016/j.mencom.2021.04.024_bib0065
Batsanov
Acta Crystallogr., 2004
14.
10.1016/j.mencom.2021.04.024_bib0070
Handbuch der praparativen anorganischen Chemie, 1978
15.
Protic Ionic Liquids:  Properties and Applications
Greaves T.L., Drummond C.J.
Chemical Reviews, 2007
18.
10.1016/j.mencom.2021.04.024_bib0090
Znamenkov
Russ. J. Inorg. Chem., 2004
19.
Very strong hydrogen bonding
Emsley J.
Chemical Society Reviews, 1980
20.
Microwave Spectrum and Structure of Nitric Acid
Cox A.P., Riveros J.M.
Journal of Chemical Physics, 1965
21.
The crystal structures of the low-temperature and high-pressure polymorphs of nitric acid
Allan D.R., Marshall W.G., Francis D.J., Oswald I.D., Pulham C.R., Spanswick C.
Dalton Transactions, 2010
22.
Modes of coordination and stereochemistry of nitrate groups in organic and organometallic nitrates
Morozov I.V., Serezhkin V.N., Troyanov S.I.
Russian Chemical Bulletin, 2009