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First example of peroxosolvate of iodine-containing organic molecule

Andrei Viktorovich Churakov 1
Andrei Viktorovich Churakov
, 
Aleksei Viktorovich Medved'ko 2
Aleksei Viktorovich Medved'ko
, 
Petr Valer'evich Prikhodchenko 1
Petr Valer'evich Prikhodchenko
,  , 
Sergey Zurabovich Vatsadze 2
Sergey Zurabovich Vatsadze
10.1016/j.mencom.2021.04.023
Published 2021-04-28
Communication , Volume 31, Issue 3, 352-355
9
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Churakov A. V. et al. First example of peroxosolvate of iodine-containing organic molecule // Mendeleev Communications. 2021. Vol. 31. No. 3. pp. 352-355.
GOST all authors (up to 50) Copy
Churakov A. V., Medved'ko A. V., Prikhodchenko P. V., Krut'ko D. P., Vatsadze S. Z. First example of peroxosolvate of iodine-containing organic molecule // Mendeleev Communications. 2021. Vol. 31. No. 3. pp. 352-355.
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TY - JOUR
DO - 10.1016/j.mencom.2021.04.023
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.04.023
TI - First example of peroxosolvate of iodine-containing organic molecule
T2 - Mendeleev Communications
AU - Churakov, Andrei Viktorovich
AU - Medved'ko, Aleksei Viktorovich
AU - Prikhodchenko, Petr Valer'evich
AU - Krut'ko, Dmitry Petrovich
AU - Vatsadze, Sergey Zurabovich
PY - 2021
DA - 2021/04/28
PB - Mendeleev Communications
SP - 352-355
IS - 3
VL - 31
ER -
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@article{2021_Churakov,
author = {Andrei Viktorovich Churakov and Aleksei Viktorovich Medved'ko and Petr Valer'evich Prikhodchenko and Dmitry Petrovich Krut'ko and Sergey Zurabovich Vatsadze},
title = {First example of peroxosolvate of iodine-containing organic molecule},
journal = {Mendeleev Communications},
year = {2021},
volume = {31},
publisher = {Mendeleev Communications},
month = {Apr},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.04.023},
number = {3},
pages = {352--355},
doi = {10.1016/j.mencom.2021.04.023}
}
MLA
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MLA Copy
Churakov, Andrei Viktorovich, et al. “First example of peroxosolvate of iodine-containing organic molecule.” Mendeleev Communications, vol. 31, no. 3, Apr. 2021, pp. 352-355. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.04.023.

Keywords

3,7-diazabicyclo[3.3.1]nonane
conformation analysis
hydrogen peroxide
organoiodine compounds
peroxosolvates
X-ray diffraction study
α-halo carbonyl compounds

Abstract

Six new bispidine-based bis-amides containing residues of haloacetic acids were synthesized and characterized by X-ray crystallography. The dissolution of iodine-containing compound in concentrated hydrogen peroxide afforded bispidine peroxosolvate, in which the peroxide molecules participated in two donor hydrogen bonds with carbonyl oxygen atoms of the distinct adjacent organic molecules thus forming cyclic motifs in crystals. This structure is a first example of peroxosolvate of iodine-containing organic molecule.

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