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Cyclobutadiene cobalt complexes as catalysts for insertion of diazo compounds into X–H bonds

Nikita Vyacheslavovich Shvydkiy 1
Nikita Vyacheslavovich Shvydkiy
, 
Dmitrii Sergeevich Perekalin 1, 2
Dmitrii Sergeevich Perekalin
10.1016/j.mencom.2021.04.022
Published 2021-04-28
Communication , Volume 31, Issue 3, 350-351
5
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Shvydkiy N. V., Perekalin D. S. Cyclobutadiene cobalt complexes as catalysts for insertion of diazo compounds into X–H bonds // Mendeleev Communications. 2021. Vol. 31. No. 3. pp. 350-351.
GOST all authors (up to 50) Copy
Shvydkiy N. V., Perekalin D. S. Cyclobutadiene cobalt complexes as catalysts for insertion of diazo compounds into X–H bonds // Mendeleev Communications. 2021. Vol. 31. No. 3. pp. 350-351.
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TY - JOUR
DO - 10.1016/j.mencom.2021.04.022
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.04.022
TI - Cyclobutadiene cobalt complexes as catalysts for insertion of diazo compounds into X–H bonds
T2 - Mendeleev Communications
AU - Shvydkiy, Nikita Vyacheslavovich
AU - Perekalin, Dmitrii Sergeevich
PY - 2021
DA - 2021/04/28
PB - Mendeleev Communications
SP - 350-351
IS - 3
VL - 31
ER -
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@article{2021_Shvydkiy,
author = {Nikita Vyacheslavovich Shvydkiy and Dmitrii Sergeevich Perekalin},
title = {Cyclobutadiene cobalt complexes as catalysts for insertion of diazo compounds into X–H bonds},
journal = {Mendeleev Communications},
year = {2021},
volume = {31},
publisher = {Mendeleev Communications},
month = {Apr},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.04.022},
number = {3},
pages = {350--351},
doi = {10.1016/j.mencom.2021.04.022}
}
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Shvydkiy, Nikita Vyacheslavovich, and Dmitrii Sergeevich Perekalin. “Cyclobutadiene cobalt complexes as catalysts for insertion of diazo compounds into X–H bonds.” Mendeleev Communications, vol. 31, no. 3, Apr. 2021, pp. 350-351. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.04.022.

Keywords

catalysis
cobalt complexes
cyclobutadiene
diazo compounds
insertion
organosilicon compounds

Abstract

Novel cyclobutadiene cobalt complex with labile naphthalene ligand [(C4Et4)Co(C10H8)]PF6 catalyzes the insertion of ethyl diazoacetate into X–H bonds giving the corresponding products in 15–75% yields. The reaction proceeds with primary and secondary aliphatic amines, hydrosilanes and triethylamine borane but not with anilines and alcohols.

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