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Selective and efficient electrocatalytic way to spirobarbituric dihydrofurans

, 
Anatoly Nikolaevich Vereshchagin 1
Anatoly Nikolaevich Vereshchagin
, 
Yuliya Evgenievna Ryzhkova 1
Yuliya Evgenievna Ryzhkova
, 
Mikhail Petrovich Egorov 1
Mikhail Petrovich Egorov
10.1016/j.mencom.2021.04.021
Published 2021-04-28
Communication , Volume 31, Issue 3, 347-349
4
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Elinson M. N. et al. Selective and efficient electrocatalytic way to spirobarbituric dihydrofurans // Mendeleev Communications. 2021. Vol. 31. No. 3. pp. 347-349.
GOST all authors (up to 50) Copy
Elinson M. N., Vereshchagin A. N., Ryzhkova Y. E., Egorov M. P. Selective and efficient electrocatalytic way to spirobarbituric dihydrofurans // Mendeleev Communications. 2021. Vol. 31. No. 3. pp. 347-349.
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TY - JOUR
DO - 10.1016/j.mencom.2021.04.021
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.04.021
TI - Selective and efficient electrocatalytic way to spirobarbituric dihydrofurans
T2 - Mendeleev Communications
AU - Elinson, Michail Nikolaevich
AU - Vereshchagin, Anatoly Nikolaevich
AU - Ryzhkova, Yuliya Evgenievna
AU - Egorov, Mikhail Petrovich
PY - 2021
DA - 2021/04/28
PB - Mendeleev Communications
SP - 347-349
IS - 3
VL - 31
ER -
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@article{2021_Elinson,
author = {Michail Nikolaevich Elinson and Anatoly Nikolaevich Vereshchagin and Yuliya Evgenievna Ryzhkova and Mikhail Petrovich Egorov},
title = {Selective and efficient electrocatalytic way to spirobarbituric dihydrofurans},
journal = {Mendeleev Communications},
year = {2021},
volume = {31},
publisher = {Mendeleev Communications},
month = {Apr},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.04.021},
number = {3},
pages = {347--349},
doi = {10.1016/j.mencom.2021.04.021}
}
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MLA Copy
Elinson, Michail Nikolaevich, et al. “Selective and efficient electrocatalytic way to spirobarbituric dihydrofurans.” Mendeleev Communications, vol. 31, no. 3, Apr. 2021, pp. 347-349. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.04.021.

Keywords

Cyclization
electrocatalysis
electrosynthesis
mediated electrolysis
spirobarbituric dihydrofurans

Abstract

Electrocatalytic cyclization of 6-hydroxy-5-[(2-hydroxy-6-oxocyclohex-1-en-1-yl)(aryl)methyl]-1,3-dimethylpyrimidine-2,4-(1H,3H)-diones in alcohols in an undivided cell in the presence of sodium halides results in selective formation of substituted spirobarbituric dihydrofurans in 82–93% yields. Crystal structure of 3-(3-bromophenyl)-1′,3′,6,6-tetramethyl-3,5,6,7-tetrahydro-2′,4-dihydrospiro[benzofuran-2,5′-pyrimidine]-2′,4,4′,6′(1′H,3′H)-tetraone has been confirmed by X-ray diffraction data.

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