Home / Publications / Effect of Freon matrices on the intermediates stabilized in X-ray irradiated 1,7-dioxaspiro[5,5]undecane solutions at 77K

Effect of Freon matrices on the intermediates stabilized in X-ray irradiated 1,7-dioxaspiro[5,5]undecane solutions at 77K

Ivan Dmitrievich Sorokin 1
Ivan Dmitrievich Sorokin
, 
Oleg Igorevich Gromov 1
Oleg Igorevich Gromov
, 
Vladimir Ivanovich Pergushov 1
Vladimir Ivanovich Pergushov
, 
Daria Anatol'evna Pomogailo 1, 2
Daria Anatol'evna Pomogailo
, 
Mikhail Yakovlevich Melnikov 1
Mikhail Yakovlevich Melnikov
10.1016/j.mencom.2021.04.020
Published 2021-04-28
Communication , Volume 31, Issue 3, 343-346
1
Share
Cite this
GOST
 | 
Cite this
GOST Copy
Sorokin I. D. et al. Effect of Freon matrices on the intermediates stabilized in X-ray irradiated 1,7-dioxaspiro[5,5]undecane solutions at 77K // Mendeleev Communications. 2021. Vol. 31. No. 3. pp. 343-346.
GOST all authors (up to 50) Copy
Sorokin I. D., Gromov O. I., Pergushov V. I., Pomogailo D. A., Melnikov M. Y. Effect of Freon matrices on the intermediates stabilized in X-ray irradiated 1,7-dioxaspiro[5,5]undecane solutions at 77K // Mendeleev Communications. 2021. Vol. 31. No. 3. pp. 343-346.
RIS
 | 
Cite this
RIS Copy
TY - JOUR
DO - 10.1016/j.mencom.2021.04.020
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.04.020
TI - Effect of Freon matrices on the intermediates stabilized in X-ray irradiated 1,7-dioxaspiro[5,5]undecane solutions at 77K
T2 - Mendeleev Communications
AU - Sorokin, Ivan Dmitrievich
AU - Gromov, Oleg Igorevich
AU - Pergushov, Vladimir Ivanovich
AU - Pomogailo, Daria Anatol'evna
AU - Melnikov, Mikhail Yakovlevich
PY - 2021
DA - 2021/04/28
PB - Mendeleev Communications
SP - 343-346
IS - 3
VL - 31
ER -
BibTex
 | 
Cite this
BibTex (up to 50 authors) Copy
@article{2021_Sorokin,
author = {Ivan Dmitrievich Sorokin and Oleg Igorevich Gromov and Vladimir Ivanovich Pergushov and Daria Anatol'evna Pomogailo and Mikhail Yakovlevich Melnikov},
title = {Effect of Freon matrices on the intermediates stabilized in X-ray irradiated 1,7-dioxaspiro[5,5]undecane solutions at 77K},
journal = {Mendeleev Communications},
year = {2021},
volume = {31},
publisher = {Mendeleev Communications},
month = {Apr},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.04.020},
number = {3},
pages = {343--346},
doi = {10.1016/j.mencom.2021.04.020}
}
MLA
Cite this
MLA Copy
Sorokin, Ivan Dmitrievich, et al. “Effect of Freon matrices on the intermediates stabilized in X-ray irradiated 1,7-dioxaspiro[5,5]undecane solutions at 77K.” Mendeleev Communications, vol. 31, no. 3, Apr. 2021, pp. 343-346. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.04.020.

Keywords

1,7-dioxaspiro[5,5]undecane
DFT
EPR spectroscopy
Freons
matrix effect
matrix stabilization
photochemistry
radical cations
reactive intermediates
UV/VIS spectroscopy

Abstract

Freon matrices affected the nature of species stabilized upon the X-ray irradiation of frozen 1,7-dioxaspiro[5,5]undecane (DOSU)/CF3CCl3 or DOSU/CFCl3 solutions at 77K. This manifested in the stabilization of a ring-closed DOSU radical cation (RC) with an absorption maximum at ∼440nm in CF3CCl3 versus a paramagnetic intermediate with no absorption in this spectral region and a notably different EPR spectrum in CFCl3. Interestingly, the ultimate product in a sequence of photochemical and thermally induced transformations was the same in both matrices: a distonic DOSU RC with a terminal alkyl fragment afforded upon C–C bond cleavage at the spiro carbon atom.

References

2.
An e.s.r. study of the trimethyl phosphate radical cation–trichlorofluoromethane σ* complex and its dissociation
Qin X., Walther B.W., Williams F.
Journal of the Chemical Society Chemical Communications, 1984
3.
An electron spin resonance study of lactone radical cations formed in .gamma.-irradiated Freon matrixes
Rideout J., Symons M.C., Swarts S., Besler B., Sevilla M.D.
The Journal of Physical Chemistry, 1985
4.
Photochemical transformations of cyclic acetal radical cations in Freon matrices at 77 K
Mel’nikov M.Y., Belokon’ E.A., Belevskii V.N., Kalugina A.D., Mel’nikova O.L., Pergushov V.I., Egorov M.P.
Moscow University Chemistry Bulletin, 2008
5.
10.1016/j.mencom.2021.04.020_sbref0020b
Belevskii
High Energy Chem., 1998
6.
The dimer cation of trichlorofluoromethane
Symons M.C., Wren B.W., Muto H., Toriyama K., Iwasaki M.
Chemical Physics Letters, 1986
7.
Electron spin resonance spectra of tetrafluoroethylene radical cation
Hasegawa A., Symons M.C.
Journal of the Chemical Society Faraday Transactions 1 Physical Chemistry in Condensed Phases, 1983
9.
Sorokin I.D., Feldman V.I., Melnikova O.L., Pergushov V.I., Tyurin D.A., Melnikov M.Y.
Mendeleev Communications, 2011
11.
A. V. Bogdanov, Orthos: software for simulation of EPR spectra, URL: http://orthos-epr.sourceforge.net/.
12.
Software update: the ORCA program system, version 4.0
Neese F.
Wiley Interdisciplinary Reviews: Computational Molecular Science, 2017
19.
Sorokin I.D., Gromov O.I., Pergushov V.I., Pomogailo D.A., Melnikov M.Y.
Mendeleev Communications, 2020
20.
10.1016/j.mencom.2021.04.020_bib0090
Melnikov
Moscow Univ. Chem. Bull. (Engl. Transl.), 2021
22.
10.1016/j.mencom.2021.04.020_bib0100
Sadovnichy
Contemporary High Performance Computing: from Petascale toward Exascale, 2013