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Facile synthesis of digermylene oxide and its reactivity towards vanadocene: the first example of Cp2V–germylene coordination

Kseniya Vital'evna Arsenyeva 1
Kseniya Vital'evna Arsenyeva
, 
Maxim Gennad'evich Chegerev 2
Maxim Gennad'evich Chegerev
, 
Anton Vladimirovich Cherkasov 1
Anton Vladimirovich Cherkasov
, 
Kira Igorevna Pashanova 1
Kira Igorevna Pashanova
, 
Irina Vasilievna Ershova 1
Irina Vasilievna Ershova
, 
Olesya Yuryevna Trofimova 1
Olesya Yuryevna Trofimova
, 
Aleksandr Vladimirovich Piskunov 1
Aleksandr Vladimirovich Piskunov
10.1016/j.mencom.2021.04.016
Published 2021-04-28
Communication , Volume 31, Issue 3, 330-333
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Arsenyeva K. V. et al. Facile synthesis of digermylene oxide and its reactivity towards vanadocene: the first example of Cp2V–germylene coordination // Mendeleev Communications. 2021. Vol. 31. No. 3. pp. 330-333.
GOST all authors (up to 50) Copy
Arsenyeva K. V., Chegerev M. G., Cherkasov A. V., Pashanova K. I., Ershova I. V., Trofimova O. Y., Piskunov A. V. Facile synthesis of digermylene oxide and its reactivity towards vanadocene: the first example of Cp2V–germylene coordination // Mendeleev Communications. 2021. Vol. 31. No. 3. pp. 330-333.
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TY - JOUR
DO - 10.1016/j.mencom.2021.04.016
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.04.016
TI - Facile synthesis of digermylene oxide and its reactivity towards vanadocene: the first example of Cp2V–germylene coordination
T2 - Mendeleev Communications
AU - Arsenyeva, Kseniya Vital'evna
AU - Chegerev, Maxim Gennad'evich
AU - Cherkasov, Anton Vladimirovich
AU - Pashanova, Kira Igorevna
AU - Ershova, Irina Vasilievna
AU - Trofimova, Olesya Yuryevna
AU - Piskunov, Aleksandr Vladimirovich
PY - 2021
DA - 2021/04/28
PB - Mendeleev Communications
SP - 330-333
IS - 3
VL - 31
ER -
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@article{2021_Arsenyeva,
author = {Kseniya Vital'evna Arsenyeva and Maxim Gennad'evich Chegerev and Anton Vladimirovich Cherkasov and Kira Igorevna Pashanova and Irina Vasilievna Ershova and Olesya Yuryevna Trofimova and Aleksandr Vladimirovich Piskunov},
title = {Facile synthesis of digermylene oxide and its reactivity towards vanadocene: the first example of Cp2V–germylene coordination},
journal = {Mendeleev Communications},
year = {2021},
volume = {31},
publisher = {Mendeleev Communications},
month = {Apr},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.04.016},
number = {3},
pages = {330--333},
doi = {10.1016/j.mencom.2021.04.016}
}
MLA
Cite this
MLA Copy
Arsenyeva, Kseniya Vital'evna, et al. “Facile synthesis of digermylene oxide and its reactivity towards vanadocene: the first example of Cp2V–germylene coordination.” Mendeleev Communications, vol. 31, no. 3, Apr. 2021, pp. 330-333. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.04.016.

Keywords

o-amidophenolate
germylene
N-heterocyclic carbene
vanadocene
X-ray diffraction

Abstract

Digermylene oxide was prepared by hydrolysis of O,N-heterocyclic germylene, and its reactivity was examined in situ. Its treatment with N-heterocyclic carbene produces dianionic digermylene oxide while its reaction with vanadocene gives the dinuclear derivative, a rare example of a compound containing the vanadium–germylene coordination bond. The product structures were confirmed by X-ray diffraction analysis.

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