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Capturing polycyclic aromatic sulfur heterocycles in electron donor–acceptor complexes

Olga Evgenievna Eremina 1
Olga Evgenievna Eremina
Mariia Vital'evna Ferree 1
Mariia Vital'evna Ferree
Tatyana Nikolaevna Shekhovtsova 1
Tatyana Nikolaevna Shekhovtsova
Irina Anatol'evna Veselova 1
Irina Anatol'evna Veselova
Published 2021-04-28
CommunicationVolume 31, Issue 3, 326-329
3
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Eremina O. E. et al. Capturing polycyclic aromatic sulfur heterocycles in electron donor–acceptor complexes // Mendeleev Communications. 2021. Vol. 31. No. 3. pp. 326-329.
GOST all authors (up to 50) Copy
Eremina O. E., Samodelova M. V., Ferree M. V., Shekhovtsova T. N., Veselova I. A. Capturing polycyclic aromatic sulfur heterocycles in electron donor–acceptor complexes // Mendeleev Communications. 2021. Vol. 31. No. 3. pp. 326-329.
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TY - JOUR
DO - 10.1016/j.mencom.2021.04.015
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.04.015
TI - Capturing polycyclic aromatic sulfur heterocycles in electron donor–acceptor complexes
T2 - Mendeleev Communications
AU - Eremina, Olga Evgenievna
AU - Samodelova, Maria V
AU - Ferree, Mariia Vital'evna
AU - Shekhovtsova, Tatyana Nikolaevna
AU - Veselova, Irina Anatol'evna
PY - 2021
DA - 2021/04/28
PB - Mendeleev Communications
SP - 326-329
IS - 3
VL - 31
ER -
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@article{2021_Eremina,
author = {Olga Evgenievna Eremina and Maria V Samodelova and Mariia Vital'evna Ferree and Tatyana Nikolaevna Shekhovtsova and Irina Anatol'evna Veselova},
title = {Capturing polycyclic aromatic sulfur heterocycles in electron donor–acceptor complexes},
journal = {Mendeleev Communications},
year = {2021},
volume = {31},
publisher = {Mendeleev Communications},
month = {Apr},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.04.015},
number = {3},
pages = {326--329},
doi = {10.1016/j.mencom.2021.04.015}
}
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Eremina, Olga Evgenievna, et al. “Capturing polycyclic aromatic sulfur heterocycles in electron donor–acceptor complexes.” Mendeleev Communications, vol. 31, no. 3, Apr. 2021, pp. 326-329. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.04.015.

Keywords

charge transfer complex
dibenzothiophene
multiplex detection
optical sensor
polycyclic aromatic sulfur heterocycles
silver nanoparticles
surface enhanced Raman spectroscopy

Abstract

Stoichiometry and stability of electron donor–acceptor complexes formed by dibenzothiophene and its alkylated derivatives with DDQ and TCNE in nonpolar organic solvents has been investigated. 4,6-Dimethyldibenzothiophene produces the most stable 1: 1 complex with DDQ in agreement with energy levels of the π-donors HOMOs and π-acceptors LUMOs calculated by DFT. The results make possible an employment of the complexes for multiplex determination of polycyclic aromatic pollutants using surface enhanced Raman spectroscopy.

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