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Influence of pyridine-based ligands on photostability of MAPbI3 thin films

Mayuribala Mangrulkar 1
Mayuribala Mangrulkar
, 
Sergey Yur'evich Luchkin 1
Sergey Yur'evich Luchkin
, 
Aleksandra Gennad'evna Boldyreva 1
Aleksandra Gennad'evna Boldyreva
,  , 
Keith J Stevenson 1
Keith J Stevenson
10.1016/j.mencom.2021.04.013
Published 2021-04-28
Communication , Volume 31, Issue 3, 319-322
5
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Mangrulkar M. et al. Influence of pyridine-based ligands on photostability of MAPbI3 thin films // Mendeleev Communications. 2021. Vol. 31. No. 3. pp. 319-322.
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Mangrulkar M., Luchkin S. Y., Boldyreva A. G., Troshin P. A., Stevenson K. J. Influence of pyridine-based ligands on photostability of MAPbI3 thin films // Mendeleev Communications. 2021. Vol. 31. No. 3. pp. 319-322.
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TY - JOUR
DO - 10.1016/j.mencom.2021.04.013
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.04.013
TI - Influence of pyridine-based ligands on photostability of MAPbI3 thin films
T2 - Mendeleev Communications
AU - Mangrulkar, Mayuribala
AU - Luchkin, Sergey Yur'evich
AU - Boldyreva, Aleksandra Gennad'evna
AU - Troshin, Pavel Anatol'evich
AU - Stevenson, Keith J
PY - 2021
DA - 2021/04/28
PB - Mendeleev Communications
SP - 319-322
IS - 3
VL - 31
ER -
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@article{2021_Mangrulkar,
author = {Mayuribala Mangrulkar and Sergey Yur'evich Luchkin and Aleksandra Gennad'evna Boldyreva and Pavel Anatol'evich Troshin and Keith J Stevenson},
title = {Influence of pyridine-based ligands on photostability of MAPbI3 thin films},
journal = {Mendeleev Communications},
year = {2021},
volume = {31},
publisher = {Mendeleev Communications},
month = {Apr},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.04.013},
number = {3},
pages = {319--322},
doi = {10.1016/j.mencom.2021.04.013}
}
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Mangrulkar, Mayuribala, et al. “Influence of pyridine-based ligands on photostability of MAPbI3 thin films.” Mendeleev Communications, vol. 31, no. 3, Apr. 2021, pp. 319-322. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.04.013.

Keywords

additive
MAPbI3
perovskite films
perovskite solar cells
pyridine-based ligand
stability
thin films

Abstract

The effect of pyridine-based ligands, capable of coordinating e improving stability with Pb2+ defect sites through nitrogen atoms, on the photostability of MAPbI3 thin films under solar radiation of 70–80mWcm−2 at 50–60°C in an inert atmosphere has been investigated using UV-VIS spectroscopy, X-ray diffraction analysis and atomic force microscopy. It has been found that the addition of 4,4′-bipyridine to the perovskite precursor improves the photostability of a MAPbI3 thin film, withstanding illumination for 1400h.

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