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Direct oxidative functionalization of saturated dispiro-cyclopropanated bicyclo[3.3.1]nonanes

Kristian Samvelovich Andriasov 1
Kristian Samvelovich Andriasov
,  , 
Marina Gennadievna Eremenko 1
Marina Gennadievna Eremenko
,  ,  , 
Tamara Stepanovna Kuznetsova 1
Tamara Stepanovna Kuznetsova
, 
Elena Borisovna Averina 1, 2
Elena Borisovna Averina
10.1016/j.mencom.2021.04.005
Published 2021-04-28
Communication , Volume 31, Issue 3, 294-296
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Andriasov K. S. et al. Direct oxidative functionalization of saturated dispiro-cyclopropanated bicyclo[3.3.1]nonanes // Mendeleev Communications. 2021. Vol. 31. No. 3. pp. 294-296.
GOST all authors (up to 50) Copy
Andriasov K. S., Sedenkova K. N., Eremenko M. G., Gloriozov I. P., Grishin Y. K., Kuznetsova T. S., Averina E. B. Direct oxidative functionalization of saturated dispiro-cyclopropanated bicyclo[3.3.1]nonanes // Mendeleev Communications. 2021. Vol. 31. No. 3. pp. 294-296.
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TY - JOUR
DO - 10.1016/j.mencom.2021.04.005
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.04.005
TI - Direct oxidative functionalization of saturated dispiro-cyclopropanated bicyclo[3.3.1]nonanes
T2 - Mendeleev Communications
AU - Andriasov, Kristian Samvelovich
AU - Sedenkova, Kseniya N
AU - Eremenko, Marina Gennadievna
AU - Gloriozov, Igor Pavlovich
AU - Grishin, Yuri Konstantinovich
AU - Kuznetsova, Tamara Stepanovna
AU - Averina, Elena Borisovna
PY - 2021
DA - 2021/04/28
PB - Mendeleev Communications
SP - 294-296
IS - 3
VL - 31
ER -
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@article{2021_Andriasov,
author = {Kristian Samvelovich Andriasov and Kseniya N Sedenkova and Marina Gennadievna Eremenko and Igor Pavlovich Gloriozov and Yuri Konstantinovich Grishin and Tamara Stepanovna Kuznetsova and Elena Borisovna Averina},
title = {Direct oxidative functionalization of saturated dispiro-cyclopropanated bicyclo[3.3.1]nonanes},
journal = {Mendeleev Communications},
year = {2021},
volume = {31},
publisher = {Mendeleev Communications},
month = {Apr},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.04.005},
number = {3},
pages = {294--296},
doi = {10.1016/j.mencom.2021.04.005}
}
MLA
Cite this
MLA Copy
Andriasov, Kristian Samvelovich, et al. “Direct oxidative functionalization of saturated dispiro-cyclopropanated bicyclo[3.3.1]nonanes.” Mendeleev Communications, vol. 31, no. 3, Apr. 2021, pp. 294-296. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.04.005.

Keywords

1,5-diketones
bicyclo[3.3.1]nonanes
Cyclopropanes
cyclopropyl ketones
methyl(trifluoromethyl)dioxirane
oxidation
ozone
ruthenium(VIII) oxide
spiro compounds

Abstract

Two dispiro[cyclopropane-1,3’-bicyclo[3.3.1]nonane-7′,1″-cyclopropanes] were treated with various oxidative systems. The conditions providing mono- or dioxidation of the CH2 groups neighbouring to spiro-annulated cyclopropane moieties to afford the corresponding mono- or diketones were found.

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