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Polymerization-induced phase separation in gradient copolymers

Mikhail Yur'evich Zaremski 1
Mikhail Yur'evich Zaremski
, 
Elena Yur'evna Kozhunova 2
Elena Yur'evna Kozhunova
, 
Sergey Savel'evich Abramchuk 2
Sergey Savel'evich Abramchuk
, 
Maria Evgenievna Glavatskaya 1
Maria Evgenievna Glavatskaya
, 
Alexander V Chertovich 2, 3
Alexander V Chertovich
10.1016/j.mencom.2021.03.045
Published 2021-03-03
Communication , Volume 31, Issue 2, 277-279
8
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Zaremski M. Y. et al. Polymerization-induced phase separation in gradient copolymers // Mendeleev Communications. 2021. Vol. 31. No. 2. pp. 277-279.
GOST all authors (up to 50) Copy
Zaremski M. Y., Kozhunova E. Y., Abramchuk S. S., Glavatskaya M. E., Chertovich A. V. Polymerization-induced phase separation in gradient copolymers // Mendeleev Communications. 2021. Vol. 31. No. 2. pp. 277-279.
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TY - JOUR
DO - 10.1016/j.mencom.2021.03.045
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.03.045
TI - Polymerization-induced phase separation in gradient copolymers
T2 - Mendeleev Communications
AU - Zaremski, Mikhail Yur'evich
AU - Kozhunova, Elena Yur'evna
AU - Abramchuk, Sergey Savel'evich
AU - Glavatskaya, Maria Evgenievna
AU - Chertovich, Alexander V
PY - 2021
DA - 2021/03/03
PB - Mendeleev Communications
SP - 277-279
IS - 2
VL - 31
ER -
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@article{2021_Zaremski,
author = {Mikhail Yur'evich Zaremski and Elena Yur'evna Kozhunova and Sergey Savel'evich Abramchuk and Maria Evgenievna Glavatskaya and Alexander V Chertovich},
title = {Polymerization-induced phase separation in gradient copolymers},
journal = {Mendeleev Communications},
year = {2021},
volume = {31},
publisher = {Mendeleev Communications},
month = {Mar},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.03.045},
number = {2},
pages = {277--279},
doi = {10.1016/j.mencom.2021.03.045}
}
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Zaremski, Mikhail Yur'evich, et al. “Polymerization-induced phase separation in gradient copolymers.” Mendeleev Communications, vol. 31, no. 2, Mar. 2021, pp. 277-279. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.03.045.

Keywords

block copolymers
gradient copolymers
microphase separation
nitroxide
polymerization-induced self-assembly

Abstract

Gradient copolymers of styrene and N-vinylpyrrolidone, obtained in bulk using the reversible deactivation radical polymerization process under the action of TEMPO nitroxide, can form microphase-like separated structures directly in the reaction medium without any additional treatment or solvent. The morphology of the resulting product is highly dependent on the monomer feed composition.

References

1.
50th Anniversary Perspective: Functional Nanoparticles from the Solution Self-Assembly of Block Copolymers
Tritschler U., Pearce S., Gwyther J., Whittell G.R., Manners I.
Macromolecules, 2017
2.
Diblock Copolymer Micelles in a Dilute Solution
Zhulina E.B., Adam M., LaRue I., Sheiko S.S., Rubinstein M.
Macromolecules, 2005
4.
Phase diagrams of block copolymer melts by dissipative particle dynamics simulations
Gavrilov A.A., Kudryavtsev Y.V., Chertovich A.V.
Journal of Chemical Physics, 2013
6.
Simulation of phase separation in melts of regular and random multiblock copolymers
Gavrilov A.A., Kudryavtsev Y.V., Khalatur P.G., Chertovich A.V.
Polymer Science - Series A, 2011
7.
Surfactant-free synthesis of amphiphilic diblock copolymer nanoparticles via nitroxide-mediated emulsion polymerization
Delaittre G., Nicolas J., Lefay C., Save M., Charleux B.
Chemical Communications, 2005
9.
Formation of polymer vesicles by simultaneous chain growth and self-assembly of amphiphilic block copolymers
Delaittre G., Dire C., Rieger J., Putaux J., Charleux B.
Chemical Communications, 2009
11.
Emerging Trends in Polymerization-Induced Self-Assembly
Penfold N.J., Yeow J., Boyer C., Armes S.P.
ACS Macro Letters, 2019
12.
Gradient copolymers: Synthesis, structure, and properties
Zaremski M.Y., Kalugin D.I., Golubev V.B.
Polymer Science - Series A, 2009
13.
Gradient copolymers by atom transfer radical copolymerization
Matyjaszewski K., Ziegler M.J., Arehart S.V., Greszta D., Pakula T.
Journal of Physical Organic Chemistry, 2000
14.
Gradient polymers and copolymers
Kryszewski M.
Polymers for Advanced Technologies, 1998
16.
Exploring Quality in Gradient Copolymers
Elsen A.M., Li Y., Li Q., Sheiko S.S., Matyjaszewski K.
Macromolecular Rapid Communications, 2013
17.
Gradient copolymers – Preparation, properties and practice
Alam M.M., Jack K.S., Hill D.J., Whittaker A.K., Peng H.
European Polymer Journal, 2019
19.
Shcherbina M.A., Bakirov A.V., Yan L., Beginn U., Zhu X., Möller M., Chvalun S.N.
Mendeleev Communications, 2015
20.
Microphase Separation and Shear Alignment of Gradient Copolymers: Melt Rheology and Small-Angle X-Ray Scattering Analysis
Mok M.M., Pujari S., Burghardt W.R., Dettmer C.M., Nguyen S.T., Ellison C.J., Torkelson J.M.
Macromolecules, 2008
21.
Gradient Polymerization–Induced Self‐Assembly: A One‐Step Approach
Xu S., Zhang T., Kuchel R.P., Yeow J., Boyer C.
Macromolecular Rapid Communications, 2019
24.
Analysis of the linear methods for determining copolymerization reactivity ratios. VII: A critical reexamination of radical copolymerizations of styrene
Braun D., Czerwinski W., Disselhoff G., Tüdős F., Kelen T., Turcsányi B.
Die Angewandte Makromolekulare Chemie, 1984
26.
Copolymerization on Selective Substrates: Experimental Test and Computer Simulations
Kozhunova E.Y., Gavrilov A.A., Zaremski M.Y., Chertovich A.V.
Langmuir, 2017
28.
Amphiphilic multicomponent molecular brushes
Ivanov I.V., Meleshko T.K., Kashina A.V., Yakimansky A.V.
Russian Chemical Reviews, 2019