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The phenomenon of negative temperature coefficient in palladium-initiated combustion of hydrogen–propane–air mixtures

Nikolai Mihailovich Rubtsov 1
Nikolai Mihailovich Rubtsov
, 
Victor Iosifovich Chernysh 1
Victor Iosifovich Chernysh
, 
Georgii Igorevich Tsvetkov 1
Georgii Igorevich Tsvetkov
,  , 
Igor Olegovich Shamshin 2
Igor Olegovich Shamshin
10.1016/j.mencom.2021.03.044
Published 2021-03-03
Communication , Volume 31, Issue 2, 274-276
3
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Rubtsov N. M. et al. The phenomenon of negative temperature coefficient in palladium-initiated combustion of hydrogen–propane–air mixtures // Mendeleev Communications. 2021. Vol. 31. No. 2. pp. 274-276.
GOST all authors (up to 50) Copy
Rubtsov N. M., Chernysh V. I., Tsvetkov G. I., Troshin K. Y., Shamshin I. O. The phenomenon of negative temperature coefficient in palladium-initiated combustion of hydrogen–propane–air mixtures // Mendeleev Communications. 2021. Vol. 31. No. 2. pp. 274-276.
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TY - JOUR
DO - 10.1016/j.mencom.2021.03.044
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.03.044
TI - The phenomenon of negative temperature coefficient in palladium-initiated combustion of hydrogen–propane–air mixtures
T2 - Mendeleev Communications
AU - Rubtsov, Nikolai Mihailovich
AU - Chernysh, Victor Iosifovich
AU - Tsvetkov, Georgii Igorevich
AU - Troshin, Kirill Yakovlevich
AU - Shamshin, Igor Olegovich
PY - 2021
DA - 2021/03/03
PB - Mendeleev Communications
SP - 274-276
IS - 2
VL - 31
ER -
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@article{2021_Rubtsov,
author = {Nikolai Mihailovich Rubtsov and Victor Iosifovich Chernysh and Georgii Igorevich Tsvetkov and Kirill Yakovlevich Troshin and Igor Olegovich Shamshin},
title = {The phenomenon of negative temperature coefficient in palladium-initiated combustion of hydrogen–propane–air mixtures},
journal = {Mendeleev Communications},
year = {2021},
volume = {31},
publisher = {Mendeleev Communications},
month = {Mar},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.03.044},
number = {2},
pages = {274--276},
doi = {10.1016/j.mencom.2021.03.044}
}
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Cite this
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Rubtsov, Nikolai Mihailovich, et al. “The phenomenon of negative temperature coefficient in palladium-initiated combustion of hydrogen–propane–air mixtures.” Mendeleev Communications, vol. 31, no. 2, Mar. 2021, pp. 274-276. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.03.044.

Keywords

active intermediate
combustion
etching
hydrogen
ignition
palladium
propane

Abstract

During the combustion of hydrogen (70–40%) + propane (30–60%) + air mixtures over palladium at a total pressure of 1–2 atm, Pd is consumed in the chemical etching reaction with active combustion intermediates. This behaviour of palladium limits its applicability in ignition devices.

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