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Phosgene-free synthesis of symmetric bis(polyfluoroalkyl) carbonates

Anna Mikhailovna Semenova 1
Anna Mikhailovna Semenova
Marina Aleksandrovna Ezhikova 1
Marina Aleksandrovna Ezhikova
Mikhail Isaakovich Kodess 1, 2
Mikhail Isaakovich Kodess
Alexander Ya Zapevalov 1
Alexander Ya Zapevalov
Alexandr Viktorovich Pestov 1, 2
Alexandr Viktorovich Pestov
Published 2021-03-03
CommunicationVolume 31, Issue 2, 257-258
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Semenova A. M. et al. Phosgene-free synthesis of symmetric bis(polyfluoroalkyl) carbonates // Mendeleev Communications. 2021. Vol. 31. No. 2. pp. 257-258.
GOST all authors (up to 50) Copy
Semenova A. M., Ezhikova M. A., Kodess M. I., Zapevalov A. Ya., Pestov A. V. Phosgene-free synthesis of symmetric bis(polyfluoroalkyl) carbonates // Mendeleev Communications. 2021. Vol. 31. No. 2. pp. 257-258.
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TY - JOUR
DO - 10.1016/j.mencom.2021.03.038
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.03.038
TI - Phosgene-free synthesis of symmetric bis(polyfluoroalkyl) carbonates
T2 - Mendeleev Communications
AU - Semenova, Anna Mikhailovna
AU - Ezhikova, Marina Aleksandrovna
AU - Kodess, Mikhail Isaakovich
AU - Zapevalov, Alexander Ya
AU - Pestov, Alexandr Viktorovich
PY - 2021
DA - 2021/03/03
PB - Mendeleev Communications
SP - 257-258
IS - 2
VL - 31
ER -
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@article{2021_Semenova,
author = {Anna Mikhailovna Semenova and Marina Aleksandrovna Ezhikova and Mikhail Isaakovich Kodess and Alexander Ya Zapevalov and Alexandr Viktorovich Pestov},
title = {Phosgene-free synthesis of symmetric bis(polyfluoroalkyl) carbonates},
journal = {Mendeleev Communications},
year = {2021},
volume = {31},
publisher = {Mendeleev Communications},
month = {Mar},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.03.038},
number = {2},
pages = {257--258},
doi = {10.1016/j.mencom.2021.03.038}
}
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Semenova, Anna Mikhailovna, et al. “Phosgene-free synthesis of symmetric bis(polyfluoroalkyl) carbonates.” Mendeleev Communications, vol. 31, no. 2, Mar. 2021, pp. 257-258. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2021.03.038.

Keywords

dialkyl carbonates
organofluorine compounds
polyfluoalkanols
titanium alkoxides
transesterification

Abstract

A phosgene-free synthesis of symmetric bis(polyfluoroalkyl) carbonates involves the transesterification of diphenyl carbonate with polyfluoroalkanols promoted by stoichiometric amounts of titanium(iv) alkoxides.

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